109536-51-8

Basic information

• Product Name: (R)-1-[(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol
• CAS NO: 109536-51-8
• Molecular Weight: 340.373
• Mol File: 109536-51-8.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: (R)-1-[(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-[(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol(109536-51-8)
• EPA Substance Registry System: (R)-1-[(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol(109536-51-8)

Safety Data

• Hazardous Substances Data: 109536-51-8(Hazardous Substances Data)

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 105-13-5 4-Methoxybenzyl alcohol 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 14686-89-6 (1,2:5,6)-di-O-isopropylidene-D-gulose 
• 2595-05-3 Diacetone D-glucose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 69940-02-9 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose 
• 329899-64-1 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 329899-60-7 (3aR,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 115693-78-2 1,2:5,6-di-O-isopropylidene-3-O-(4-methoxybenzyl)-α-D-glucofuranose 

Downstream Products

• 82529-87-1 (3aR,5S,6S,6aR)-6-(4-methoxybenzyloxy)-tetrahydro-2,2-dimethylfuro[2,3-d][1,3]dioxole-5-carbaldehyde 
• 82529-87-1 (3aR,6S,6aR)-6-(4-Methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde 
• 109536-52-9 1,2-O-isopropylidene-3-O-(p-methoxybenzyl)-α-D-ribofuranose 
• 154799-94-7 3-O-(4-Methoxybenzyl)-1,2-O-isopropylidene-4-formylerythrofuranose 
• 82530-09-4 1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-6-O-(p-tolylsulfonyl)-α-D-glucofuranose 
• 199458-24-7 Toluene-4-sulfonic acid (R)-2-hydroxy-2-[(3aR,5R,6R,6aR)-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-ethyl ester 
• 205934-52-7 1,2-O-isopropylidene-5,6-di-O-methanesulfonyl-3-O-(4-methoxybenzyl)-α-D-allofuranose 
• 500187-73-5 C₃₁H₃₆O₁₁S₂ 
• 851393-61-8 (1R,3SR,4S,7R)-3-methoxy-7-(p-methoxybenzyloxy)-1-(p-methoxybenzyloxymethyl)-2,5-dioxabicyclo[2.2.1]heptane 
• 676126-64-0 (2S,3R,4R)-4-hydroxy-3-(p-methoxybenzyloxy)-4-(p-methoxybenzyloxymethyl)tetrahydrofuran-2-carbaldehyde 
• 676126-48-0 1,2-O-isopropylidene-5-O-methanesulfonyl-4-C-methanesulfonyloxymethyl-3-O-(p-methoxybenzyl)-β-L-threo-pentofuranose 
• 676126-71-9 (1R,3S,4R,7R)-7-(p-methoxybenzyloxy)-1-(p-methoxybenzyloxymethyl)-3-phenyl-2,5-dioxabicyclo[2.2.1]heptane 
• 676126-67-3 (2S,3R,4R)-4-hydroxy-2-(phenylcarbonyl)-3-(p-methoxybenzyloxy)-4-(p-methoxybenzyloxymethyl)tetrahydrofuran 
• 676126-69-5 (2R,3R,4R)-4-hydroxy-2-[(R)-hydroxy(phenyl)methyl]-3-(p-methoxybenzyloxy)-4-(p-methoxybenzyloxymethyl)tetrahydrofuran 

Relevant articles and documents

Yb(OTf)3·H2O: A novel reagent for the chemoselective hydrolysis of isopropylidene acetals

A facile chemoselective hydrolysis of terminal isopropylidene acetals has been achieved using a catalytic amount of Yb(OTf)3·H2O in acetonitrile at ambient temperature.

Sulfuric acid immobilized on silica: an efficient reusable catalyst for selective hydrolysis of the terminal O-isopropylidene group of sugar derivatives

Sulfuric acid immobilized on silica proved to be an efficient catalyst for selective hydrolysis of the terminal O-isopropylidene group of sugar derivatives. The method is very simple and economic for large-scale synthesis in which the catalyst is recovered and reused for several runs. Reactions with di-O-isopropylidene derivatives of d-glucose, d-mannose, d-fructose and l-sorbose led to the formation of the corresponding mono-O-isopropylidene derivatives in good to excellent yields.

ADENINE DERIVATIVE OR PHARMACOLOGICALLY ACCEPTABLE SALT THEREOF, AND PRODUCTION METHOD AND USE OF THE SAME

PROBLEM TO BE SOLVED: To provide an adenine derivative represented by general formula (I) or a pharmacologically acceptable salt thereof. SOLUTION: This invention provides an adenine derivative represented by general formula (I) or a pharmacologically acc

Synthesis of imidazo[2,1-b]thiazoles linked to an unprotected carbohydrate moiety

Two series of imidazo[2,1-b]thiazoles substituted on C-3 or C-5 with an unprotected carbohydrate moiety were synthesized. Different protective groups for position 3 of the carbohydrate moiety were tested (acetyl, tert-butyldimethylsilyl (TBDMS), and p-met