109638-21-3

Basic information

• Product Name: 2-(Benzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en
• Synonyms: 2-(Benzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en
• CAS NO: 109638-21-3
• Molecular Weight: 257.332
• Mol File: 109638-21-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(Benzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Benzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en(109638-21-3)
• EPA Substance Registry System: 2-(Benzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en(109638-21-3)

Safety Data

• Hazardous Substances Data: 109638-21-3(Hazardous Substances Data)

Upstream product

• 109638-19-9 3,3-Dimethyl-2-azabicyclo<2.2.2>oct-5-en-hydrochlorid 
• 94-36-0 dibenzoyl peroxide 
• 109638-20-2 3,3-Dimethyl-2-azabicyclo<2.2.2>oct-5-en-2-oxyl 
• 109638-18-8 3,3-Dimethyl-2-nitroso-2-azabicyclo<2.2.2>oct-5-en 
• 98-88-4 benzoyl chloride 
• 105731-48-4 3,3-Dimethyl-2-azabicyclo<2.2.2>oct-5-en-2-ol 

Downstream Products

• 109638-25-7 2-Benzoyl-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en 
• 109638-37-1 exo-2-(Benzoyloxy)-8,8-dimethyl-1-azabicyclo<3.2.1>oct-6-en 
• 105731-49-5 8,8-Dimethyl-exo-6-(4-methylphenylsulfonyloxy)-1-azatricyclo<3.2.1.0^2,7>octan 
• 105815-52-9 8,8-Dimethyl-endo-6(4-methylphenylsulfonyloxy)-1-azatricyclo<3.2.1.0^2,7>octan 
• 105731-53-1 2-(3,5-Dinitrobenzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en 
• 105731-54-2 exo-2-(3,5-Dinitrobenzoyloxy)-8,8-dimethyl-1-azabicyclo<3.2.1>oct-6-en 
• 109638-29-1 2-(3,5-Dinitrobenzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>octan 
• 105731-51-9 3,3-Dimethyl-2-(4-nitrobenzoyloxy)-2-azabicyclo<2.2.2>oct-5-en 
• 109638-22-4 2-(3,5-Dimethoxybenzoyloxy)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en 
• 109638-43-9 2,2-Dimethyl-1-(4-nitronemzoyl)-3-pyrrolidinpropanal 
• 105731-52-0 8,8-Dimethyl-exo-2-(4-nitrobenzoyloxy)-1-azabicyclo<3.2.1>oct-6-en 
• 109638-26-8 2-(3,5-Dimethoxybenzoyl)-3,3-dimethyl-2-azabicyclo<2.2.2>oct-5-en 
• 109638-38-2 exo-2-(3,5-Dimethoxybenzoyloxy)-8,8-dimethyl-1-azabicyclo<3.2.1>oct-6-en 
• 109638-33-7 2-(3,5-Dimethoxybenzoyl)-3,3-dimethyl-2-azabicyclo<2.2.2>octan 

Relevant articles and documents

Consecutive and Parallel Rearrangements of 2-Azabicyclooctane Derivatives

Derivatives of both 2-azabicyclooct-5-ene and -octane bearing electronegative substituents on nitrogen show several types of rearrangements: 1) Ring closure to the aziridine derivative 14. 2) Consecutive rearrangement of 14 to 6-azabicyclooctanes 15. 3) Rearrangement to 1-azabicyclooct-2-ene 17 and -oct-6-ene systems 19. 4) Oxygen elimination from O-acylhydroxylamines to the corresponding amides (e.g. 12c -> 13c).We have examined these rearrangements especially with the help of 18O labelled educts and MINDO/3 calculations.They occur mostly via ion pairs of different types.The intermediacy of nitrenium ions was excluded.