109739-47-1Relevant academic research and scientific papers
REACTION BETWEEN 2-HYDROXY ESTERS OF HYPOPHOSPHOROUS ACID AND ALCOHOLS
Devedjiev, I.,Borisov, G.
, p. 37 - 42 (2007/10/02)
A study of the reaction between esters of hypophosphorous acid and alcohols is carried out.It has been established that the 2-hydroxy esters of hypophosphorous acid react with alcohols as a result of which phosphonous acids are formed.A possible scheme of this reaction is suggested.
ON THE INTERACTION BETWEEN HYPOPHOSPHOROUS ACID AND ALCOHOLS
Devedjiev, I.,Ganev, V.,Stefanova, R.,Borisov, G.
, p. 7 - 12 (2007/10/02)
The esterification of hypophosphorous acid with alcohols, i.e. isopropanol, isobutanol, n-pentanol, n-octanol and 1,3-propylene glycol leads to the formation of the corresponding phosphonous acid esters in yields of up to 50percent, in addition to the hypophosphorous acid esters.The compounds are characterized by their elemental analyses, infrared and 1H NMR spectra.A mechanism of their formation is suggested.
