109802-71-3Relevant academic research and scientific papers
DIMERIZATION OF (E)-2-BENZENESULFONYL-1,3-ALKADIENES. THE BENZENESULFONYL GROUP EXERTS ACYCLIC STEREOCONTROL
Hoffmann, H. Martin R.,Weichert, Andreas,Slawin, Alexandra M. Z.,Williams, D. J.
, p. 5591 - 5602 (2007/10/02)
Mild dehydration of 2-benzenesulfonyl allylic alcohols 8 afforded a series of (E)-2-benzenesulfonyl-1,3-alkadienes 1 which dimerized to functionalized vinylcyclohexenes 3 in regio- and stereodefined manner.The configuration at C-3 in 3e was determined by
SELENOSULFONATION OF 1,3-DIENES: ONE-POT SYNTHESIS OF 2-(PHENYLSULFONYL)-1,3-DIENES
Baeckvall, Jan-E.,Najera, Carmen,Yus, Miguel
, p. 1445 - 1448 (2007/10/02)
A one-pot procedure for the transformation of a 1,3-diene into the corresponding 2-(phenylsulfonyl)-1,3-diene was developed.The reaction involves a 1,2-selenosulfonation-oxidation sequence.
