97072-36-1

Upstream product

• 16212-05-8 (allylsulfonyl)benzene 
• 107-06-2 1,2-dichloro-ethane 
• 106-93-4 ethylene dibromide 
• 109802-71-3 2-Benzenesulfonyl-1,3-butadiene 
• 70775-39-2 dimethylsulfoxonium methylide 
• 931-59-9 benzenesulfenyl chloride 
• 136339-34-9 (5-Chloro-penta-1,2-diene-3-sulfonyl)-benzene 
• 136339-07-6 (5-Iodo-penta-1,2-diene-3-sulfonyl)-benzene 

Relevant academic research and scientific papers

Regioselective cyclopropanation of 2-phenylsulfonyl 1,3-dienes

Regioselective cyclopropanation of 2-phenylsulfonyl 1,3-dienes at either double bond was achieved by employing two different reagent. Sulfur ylide 1 resulted in a regiospecific cyclopropanation at the electron deficient double bond whereas an iron carbene

Radical cyclizations of functionalized allenes

Substitution of P(O)Ph2, SOPh, and SO2Ph on an allene facilitates intramolecular radical addition to the central allene carbon to provide good yields of five-, six-, and seven-membered carbocycles.

Geminal Alkylations: Substitutions of Allyl Sulfones. Regiocontrol via Molybdenum Catalysis

Base-catalyzed geminal alkylation of allyl sulfones combined with the ability of molybdenum to direct nucleophilic substitution of the sulfone converts allyl sulfones into 1,1- and 1,3-dipole synthons.