109802-83-7

Upstream product

• 18424-76-5 sodiodimethylmalonate 
• 78776-44-0 trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate 
• 18424-76-5 dimethyl malonate sodium salt 
• 102860-22-0 2-phenylsulfonyl-1,3-cyclohexadiene 
• 108-59-8 malonic acid dimethyl ester 
• 132541-04-9 cis-1-acetoxy-4-(dicarbomethoxymethyl)-2-cyclohexene 
• 102815-53-2 3-(phenylsulfonyl)-4-(chloromercuri)cyclohexene 
• 109802-75-7 dimethyl (trans-2-(phenylsulfonyl)cyclohex-3-en-1-yl)malonate 

Relevant academic research and scientific papers

Palladium-catalyzed substitution of allylic fluorides

As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladiumcatalyzed substitution. Their activity towards this reaction fits in the series OCO2Me>OBz? F? OAc. The classic stereoretention mechanis

Asymmetric allylic alkylation of cycloalkenediol diacetates using a chiral phosphine ligand bearing a carboxyl group

Asymmetric induction in the allylic alkylation of cycloalkenediol diacetates was performed using a chiral alkylphosphine ligand bearing a carboxyl group, 3-(diphenylphosphino)butanoic acid. An increase in enantiomeric excess of the monoalkylated products of cis-cycloalkenediol diacetates was observed through a sequential asymmetric allylic alkylation- kinetic resolution process. (C) 2000 Elsevier Science Ltd.