132541-04-9

Upstream product

• 1165952-91-9 cyclohexa-1,3-diene 
• 18424-76-5 dimethyl malonate sodium salt 
• 18424-76-5 sodiodimethylmalonate 
• 82736-39-8 cis-1-acetoxy-4-chlorocyclohex-2-ene 

Downstream Products

• 97399-13-8 2-[(1S,4R)-4-(Toluene-4-sulfonylamino)-cyclohex-2-enyl]-malonic acid dimethyl ester 
• 104307-70-2 dimethyl (2,4-cyclohexadien-1-yl)malonate 
• 104307-72-4 2-(2,4-cyclohexadienyl)acetic acid methyl ester 
• 122851-17-6 2-((1S,4R)-4-Acetoxy-cyclohex-2-enyl)-2-methoxycarbonyl-4-oxo-hexanedioic acid dimethyl ester 
• 125974-31-4 O-benzyl N-<2-(2,4-cyclohexadienyl)ethyl>carbamate 
• 125974-41-6 1-(benzyloxycarbonyl)-r-5-chloro-2,3,c-3a,4,5,c-7a-hexahydroindole 
• 63814-03-9 1,2,3,3a,4,5,12b,12c-octahydro-7H-1,3-benzodioxolo[5,6-c]pyrrolo[3,2,1-ij]quinoline 
• 141612-30-8 2-(2,4-cyclohexadienyl)ethanol 
• 132541-07-2 1-(2,4-cyclohexadienyl)-2-phthalimidoethane 
• 132541-08-3 <2-(2,4-cyclohexadienyl)ethyl>ammonium chloride 
• 132541-12-9 1-(benzyloxycarbonyl)-r-7-<3,4-(methylenedioxy)phenyl>-2,3,t-3a,4,5,6,7,t-7a-octahydroindole 
• 132541-11-8 1-(benzyloxycarbonyl)-r-7-<3,4-(methylenedioxy)phenyl>-2,3,t-3a,4,7,t-7a-hexahydroindole 
• 132541-11-8 1-(benzyloxycarbonyl)-r-7-<3,4-(methylenedioxy)phenyl>-2,3,c-3a,4,7,c-7a-hexahydroindole 
• 104307-74-6 (2,4-cyclohexadienyl)-acetic acid 

Relevant academic research and scientific papers

Palladium-catalyzed substitution of allylic fluorides

As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladiumcatalyzed substitution. Their activity towards this reaction fits in the series OCO2Me>OBz? F? OAc. The classic stereoretention mechanis

Stereoselective Synthesis of Vinylcyclopropanes via Palladium-Catalyzed Reactions

Vinylcyclopropanes were synthesized in a stereocontrolled manner from 1-acetoxy-4-chloro-2-alkenes.A stereospecific palladium-catalyzed substitution of the chloro group by dimethyl malonate anion and subsequent palladium-catalyzed cyclization afforded the

STEREOSPECIFIC PALLADIUM-CATALYZED 1,4-ACETOXYCHLORINATION OF 1,3-DIENES

Palladium-catalyzed oxidation of 1,3-dienes in acetic acid in the presence of LiCl and LiOAc produces 1-acetoxy-4-chloro-2-alkenes in high selectivity.The 1,4-adducts were stereo- and regioselectively functionalized.