109810-16-4Relevant articles and documents
Atropisomerism in 3,4,5-Tri-(2-methoxyphenyl)-2,6-lutidine
Roszkowski, Piotr,Blachut, Dariusz,Maurin, Jan K.,Woznica, Magdalena,Frelek, Jadwiga,Plucinski, Franciszek,Czarnocki, Zbigniew
, p. 7867 - 7871 (2013)
Suzuki reaction of tribromo-2,6-lutidine with (2-methoxyphenyl)boronic acid gave 3,4,5-tris(2-methoxyphenyl)-2,6-lutidine in the form of a mixture of three atropisomers that were stable at room temperature. Each isomer was isolated and fully characterized
Zinc-catalyzed reaction of isoxazoles with thioynol ethers involving an unprecedented 1,2-sulfur migration
Zhu, Xin-Qi,Sun, Qing,Zhang, Zhi-Xin,Zhou, Bo,Xie, Pei-Xi,Shen, Wen-Bo,Lu, Xin,Zhou, Jin-Mei,Ye, Long-Wu
supporting information, p. 7435 - 7438 (2018/07/13)
A novel zinc-catalyzed reaction of isoxazoles with thioynol ethers involving an unprecedented 1,2-sulfur migration has been developed, which represents the first example of a non-noble metal-catalyzed reaction between isoxazoles and alkynes. This method a
Rhodium(III)-catalyzed synthesis of pyridines from α,β- unsaturated ketoximes and internal alkynes
Too, Pei Chui,Noji, Toshiharu,Lim, Ying Jie,Li, Xingwei,Chiba, Shunsuke
supporting information; experimental part, p. 2789 - 2794 (2012/01/11)
A method for the synthesis of highly substituted pyri-dines from ,-unsaturated oximes and internal alkynes has been developed using [Cp*RhCl2]2-CsOPiv as the catalyst system. The present transformation is carried out by a redox-neutral sequence of vinylic C-H rhodation, alkyne insertion, and C-N bond formation of the putative vinyl rhodium intermediate with the oxime nitrogen, where the N-O bond of oxime derivatives could work as an internal oxidant to maintain the catalytic cycle. Georg Thieme Verlag Stuttgart · New York.
A Suzuki-Miyaura approach to a series of forensically relevant pyridines
Blachut, Dariusz,Czarnocki, Zbigniew,Wojtasiewicz, Krystyna
, p. 2855 - 2864 (2008/02/07)
A convenient and general method for the preparation of sixteen 3,5-diarylsubstituted 2,4- and 2,6-dimethylpyridines of high forensic importance is described. The Suzuki cross-coupling reaction between a range of ring-substituted phenylboronic acids and 3,
STUDIES ON THE REACTION OF N-VINYLIMIDOYL COMPOUNDS WITH ACETYLENIC DIENOPHILES
Zielinski, W.,Mazik, M.
, p. 1113 - 1119 (2007/10/02)
The reaction of N-vinylimidoyl compounds with acetylene derivatives as a potential method of pyridine moiety synthesis has been examined.The mechanism of the reaction has been discussed basing on the net atomic charges determined by MNDO method for the substrates and intermediate products and the experimental data.