109810-69-7

Basic information

• Product Name: N-(2-phenylnaphthalen-1-yl)acetamide
• CAS NO: 109810-69-7
• Molecular Weight: 261.323
• Mol File: 109810-69-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(2-phenylnaphthalen-1-yl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-phenylnaphthalen-1-yl)acetamide(109810-69-7)
• EPA Substance Registry System: N-(2-phenylnaphthalen-1-yl)acetamide(109810-69-7)

Safety Data

• Hazardous Substances Data: 109810-69-7(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 1956-40-7 1-(1-naphthalenyl)ethanone oxime 
• 144930-50-7 mesityl(phenyl)iodonium triflouromethanesulfonate 
• 213272-97-0 N-(3,4-dihydro-1-naphthyl)acetamide 
• 1268358-26-4 C₂₀H₁₉NO₃ 
• 98-80-6 phenylboronic acid 
• 74886-75-2 1-nitro-2-phenylnaphthalene 

Downstream Products

• 59115-71-8 benzo[c]phenanthridin-6-ol 
• 218-38-2 benzo[c]phenanthridine 

Relevant articles and documents

One pot synthesis of phenanthridines using a palladium-catalyzed cyclization of aromatic ketoximes with aryl iodides: Via Beckmann rearrangement

The catalytic reaction of ketoximes with aryl iodides via a Beckmann rearrangement in the presence of a catalytic amount of Pd(OAc)2, Ag2O and ZnBr2 gave substituted phenanthridines in good to excellent yield. In the reaction, aromatic ketoximes converted first to acetanilides in the presence of ZnBr2/TFA via a Beckmann rearrangement followed by arylation in the presence of palladium complex. Furthermore, ortho-arylated acetanilides were converted to phenanthridine derivatives in the presence of a Hendrickson reagent.

Pd(0)-catalyzed [1,5]-sigmatropic hydrogen shift of propargylic esters toward substituent naphthylamines

A novel and convenient carboannulation method for the synthesis of highly substituted naphthylamine derivatives has been developed though a Pd(0)-catalyzed [1,5]-sigmatropic hydrogen shift and cyclization reaction of propargyl esters.