1956-40-7

Basic information

• Product Name: Ethanone, 1-(1-naphthalenyl)-, oxiMe
• Synonyms: Ethanone, 1-(1-naphthalenyl)-, oxiMe;1-Acetylnaphthalene oxiMe;1'-Acetonaphthone, oxime;(E)-1-(naphthalen-1-yl)ethan-1-one oxime
• CAS NO: 1956-40-7
• Molecular Formula: C₁₂H₁₁NO
• Molecular Weight: 185.22184
• Mol File: 1956-40-7.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 359.2°Cat760mmHg
• Flash Point: 225.5°C
• Appearance: /
• Density: 1.09g/cm³
• Vapor Pressure: 8.76E-06mmHg at 25°C
• Refractive Index: 1.579
• CAS DataBase Reference: Ethanone, 1-(1-naphthalenyl)-, oxiMe(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(1-naphthalenyl)-, oxiMe(1956-40-7)
• EPA Substance Registry System: Ethanone, 1-(1-naphthalenyl)-, oxiMe(1956-40-7)

Safety Data

• Hazardous Substances Data: 1956-40-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H11NO/c1-9(13-14)11-8-4-6-10-5-2-3-7-12(10)11/h2-8,14H,1H3

Upstream product

• 941-98-0 1'-naphthacetophenone 
• 546-88-3 acetylhydroxamic acid 
• 79-24-3 Nitroethane 
• 91-20-3 naphthalene 

Downstream Products

• 575-36-0 1-acetamidonaphthalene 
• 82572-09-6 C₂₄H₂₀NOP 
• 941-98-0 1'-naphthacetophenone 
• 942066-01-5 N-[(E)-1-(1-naphthyl)ethylidene]diphenylphosphinic amide 
• 1295522-08-5 1-methyl-3,4-diphenylbenzo[h]isoquinoline 
• 82598-06-9 (S)-(+)-N-<1-(1-Naphthyl)-ethyl>-diphenylphosphinamide 
• 23943-58-0 (R)-N-(1-naphthalen-1-ylethyl)-p,p-diphenylphosphinc amide 
• 88827-09-2 1-(naphthalen-1-yl)-N-(1-phenylethyl)ethan-1-imine 
• 109810-69-7 N-(2-phenylnaphthalen-1-yl)acetamide 
• 10319-80-9 thioacetic acid 1-naphthyl amide 
• 82572-04-1 (R)-<1-(1-Naphthyl)ethyl>ammonium chloride 
• 1073144-62-3 (1R)-1-(naphthalen-1-yl)ethanamine (R)-mandelate 
• 1243166-48-4 (1S)-1-(naphthalen-1-yl)ethanamine (R)-mandelate 
• 127104-40-9 (R*,R*)-N-hydroxy-<1(1-naphthyl)ethyl>-1-phenylethanamine 

Relevant articles and documents

Synthesis of 5-Vinyl-2-isoxazolines by Palladium-Catalyzed Intramolecular O-Allylation of Ketoximes

An efficient method for the synthesis of 5-vinyl-2-isoxazolines by Pd-catalyzed intramolecular O-allylation of ketoximes has been developed. The reaction involves Pd(0)-catalyzed π-allyl formation via leaving group ionization or Pd(II)-catalyzed allylic C-H activation followed by intramolecular nucleophilic oxime oxygen attack. This methodology has been elaborated to various value-added products by epoxidation, Wacker oxidation, cross-metathesis, hydroboration-oxidation, dihydroxylation, and catalytic hydrogenation.

CuCl2-catalyzed N[sbnd]O bond cleavage of oxime esters: Approach to imidazoheterocycles and furo[3,2-c]chromenyl fused imidazoles

An articulate approach to a diverse set of imidazoheterocycles in good to high yields via a copper-catalyzed aza-annulation of several oxime esters with a group of 2-amino-azaarenes was developed. The above cyclization reaction probably proceeds via a single electron transfer process which embodies a new technique for creating two new C[sbnd]N bonds for imidazole ring synthesis. Gratifyingly, the implementation of this chemistry could be further stretched to the synthesis of a novel class of fused imidazoles bearing a furo[3,2-c]chromene moiety via a sequential C[sbnd]N bond formation, followed by C(sp2)-H functionalization/5-endo-dig-oxacyclization (C[sbnd]C and C[sbnd]O bonds) of in situ produced fused imidazoles with cyclic enynones in the presence of copper(II) as a π-electrophilic Lewis acid catalyst.

SO2F2-Activated Efficient Beckmann Rearrangement of Ketoximes for Accessing Amides and Lactams

A novel, mild and practical protocol for the efficient activation of the Beckmann rearrangement utilizing the readily available and economical sulfuryl fluoride (SO2F2 gas) has been developed. The substrate scope of the operationally simple methodology has been demonstrated by 37 examples with good to nearly quantitative isolated yields (over 90 % yield in most cases) in a short time, including B(OH)2, COOH, NH2, and OH substituted substrates. A tentative mechanism was proposed involving formation and elimination of key intermediate, sulfonyl ester.