109845-54-7Relevant academic research and scientific papers
β-Carboline-directed decarboxylative acylation of: Ortho -C(sp2)-H of the aryl ring of aryl(β-carbolin-1-yl)methanones with α-ketoacids under palladium catalysis
Kolle, Shivalinga,Batra, Sanjay
, p. 50658 - 50665 (2016/06/09)
A palladium-catalysed β-carboline directed decarboxylative acylation of ortho-C(sp2)-H of the aryl ring of aryl(β-carbolin-1-yl)methanones using α-oxocarboxylic acid as the acyl ion equivalent to form (2-aroylaryl)(β-carbolin-2-yl)methanones is described. The utility of these products for preparing β-carboline-tethered phthalazine systems is also demonstrated.
Palladium-catalyzed acylation of sp2 C-H bond: Direct access to ketones from aldehydes
Jia, Xiaofei,Zhang, Shouhui,Wang, Wenhui,Luo, Fang,Cheng, Jiang
supporting information; experimental part, p. 3120 - 3123 (2009/12/06)
A palladium-catalyzed direct access to ketones from aldehydes via C-H cleavage of arenes is described. The procedure utilizes air as a clean and free terminal oxidant.
