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110-25-8

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110-25-8 Usage

Chemical Properties

light yellow liquid

Uses

2-(N-Methyloleamido)acetic acid (cas# 110-25-8) is used as an anti-tarnishing sunscreen additive for lubricating oil and grease.

Check Digit Verification of cas no

The CAS Registry Mumber 110-25-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 0 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 110-25:
(5*1)+(4*1)+(3*0)+(2*2)+(1*5)=18
18 % 10 = 8
So 110-25-8 is a valid CAS Registry Number.
InChI:InChI=1/C21H39NO3/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-20(23)22(2)19-21(24)25/h10-11H,3-9,12-19H2,1-2H3,(H,24,25)/b11-10-

110-25-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(N-Methyloleamido)acetic acid

1.2 Other means of identification

Product number -
Other names N-OLEOYLSARCOSINE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Corrosion inhibitors and anti-scaling agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-25-8 SDS

110-25-8Synthetic route

N-oleoylsarcosine methyl ester

N-oleoylsarcosine methyl ester

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

Conditions
ConditionsYield
Stage #1: N-oleoylsarcosine methyl ester With lithium hydroxide In ethanol; water at 20℃; for 12h;
Stage #2: With hydrogenchloride In water pH=2;
98%
sodium sarcosinate
4316-73-8

sodium sarcosinate

oleic acid chloride

oleic acid chloride

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

Conditions
ConditionsYield
With water; sodium hydroxide In toluene at 30℃; for 1h; Solvent;97.8%
(Z)-9-octadecenoyl chloride
112-77-6

(Z)-9-octadecenoyl chloride

sarcosine
107-97-1

sarcosine

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

Conditions
ConditionsYield
With sodium hydroxide
sarcosine
107-97-1

sarcosine

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

sodium sarcosinate
4316-73-8

sodium sarcosinate

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

Conditions
ConditionsYield
In water; isopropyl alcohol
(Z)-9-octadecenoyl chloride
112-77-6

(Z)-9-octadecenoyl chloride

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: N-ethyl-N,N-diisopropylamine / dichloromethane; methanol / 0 - 20 °C
2.1: lithium hydroxide / ethanol; water / 12 h / 20 °C
2.2: pH 2
View Scheme
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

6-nitroveratryl alcohol
1016-58-6

6-nitroveratryl alcohol

4,5-dimethoxy-2-nitrobenzyl [methyl(oleoyl)amino]acetate
1413644-53-7

4,5-dimethoxy-2-nitrobenzyl [methyl(oleoyl)amino]acetate

Conditions
ConditionsYield
Stage #1: N-oleoylsarcosine With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃; Inert atmosphere;
Stage #2: 6-nitroveratryl alcohol In dichloromethane at 20℃; Inert atmosphere;
82%
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

2-ethylhexyl N-oleoylsarcosinate

2-ethylhexyl N-oleoylsarcosinate

Conditions
ConditionsYield
at 150℃; for 3h; Inert atmosphere; Dean-Stark;
at 150℃; for 3h; Dean-Stark; Inert atmosphere;421.7 g
at 150℃; for 3h; Dean-Stark; Inert atmosphere;421.7 g
at 150℃; for 3h; Dean-Stark; Inert atmosphere; Reflux;421.7 g
2-Ethylhexylamine
104-75-6

2-Ethylhexylamine

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

N'-2-ethylhexyl N-oleoylsarcosinamide

N'-2-ethylhexyl N-oleoylsarcosinamide

Conditions
ConditionsYield
at 130℃; for 3h; Inert atmosphere; Dean-Stark;
at 130℃; for 3h; Dean-Stark; Inert atmosphere;266.6 g
at 130℃; for 3h; Dean-Stark; Inert atmosphere;266.6 g
at 130℃; for 3h; Dean-Stark; Inert atmosphere;266.6 g
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

N',N' bis(2-hydroxyethyl) N-oleoylsarcosinamide

N',N' bis(2-hydroxyethyl) N-oleoylsarcosinamide

Conditions
ConditionsYield
With Amberlyst 15 acidic resin at 150℃; for 3h; Inert atmosphere; Dean-Stark;
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;371.6 g
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;371.6 g
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;371.6 g
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

butan-1-ol
71-36-3

butan-1-ol

butyl N-oleoylsarcosinate

butyl N-oleoylsarcosinate

Conditions
ConditionsYield
With Amberlyst 15 acidic resin for 3h; Inert atmosphere; Dean-Stark; Reflux;310 g
With Amberlyst 15 acidic resin for 3h; Dean-Stark; Reflux; Inert atmosphere;310 g
With Amberlyst 15 acidic resin for 3h; Dean-Stark; Inert atmosphere; Reflux;310 g
With Amberlyst 15 acidic resin for 3h; Dean-Stark; Inert atmosphere; Reflux;310 g
ethanol
64-17-5

ethanol

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

ethyl N-oleoylsarcosinate

ethyl N-oleoylsarcosinate

Conditions
ConditionsYield
for 3h; Inert atmosphere; Dean-Stark; Reflux;280 g
for 3h; Dean-Stark; Inert atmosphere; Reflux;280 g
for 3h; Dean-Stark; Inert atmosphere; Reflux;280 g
for 3h; Dean-Stark; Inert atmosphere; Reflux;280 g
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

2-methoxyethyl N-oleoylsarcosinate

2-methoxyethyl N-oleoylsarcosinate

Conditions
ConditionsYield
With Amberlyst 15 acidic resin at 160℃; for 3h; Inert atmosphere; Dean-Stark;
With Amberlyst 15 acidic resin at 160℃; for 3h; Dean-Stark; Inert atmosphere;273.5 g
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

ethylene glycol
107-21-1

ethylene glycol

2-hydroxyethyl N-oleoylsarcosinate

2-hydroxyethyl N-oleoylsarcosinate

Conditions
ConditionsYield
With Amberlyst 15 acidic resin at 160℃; for 3h; Inert atmosphere; Dean-Stark;
With Amberlyst 15 acidic resin at 160℃; for 3h; Dean-Stark; Inert atmosphere;312.7 g
With Amberlyst 15 acidic resin at 160℃; for 3h; Dean-Stark; Inert atmosphere;312.7 g
With Amberlyst 15 acidic resin at 160℃; for 3h; Dean-Stark; Inert atmosphere;312.7 g
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

2-methoxyethylamine
109-85-3

2-methoxyethylamine

N'-2-methoxyethyl N-oleoylsarcosinamide

N'-2-methoxyethyl N-oleoylsarcosinamide

Conditions
ConditionsYield
With Amberlyst 15 acidic resin at 150℃; for 3h; Inert atmosphere; Dean-Stark;
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;263.9 g
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;263.9 g
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark;263.9 g
N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

1-amino-3-(dimethylamino)propane
109-55-7

1-amino-3-(dimethylamino)propane

N-oleoyl-N'-3-(dimethylamino)propylsarcosinamide

N-oleoyl-N'-3-(dimethylamino)propylsarcosinamide

Conditions
ConditionsYield
With Amberlyst 15 acidic resin at 150℃; for 3h; Inert atmosphere; Dean-Stark;
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;377.8 g
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;377.8 g
With Amberlyst 15 acidic resin at 150℃; for 3h; Dean-Stark; Inert atmosphere;377.8 g
2-(2-methoxyethoxy)ethyl alcohol
111-77-3

2-(2-methoxyethoxy)ethyl alcohol

N-oleoylsarcosine
110-25-8

N-oleoylsarcosine

2-methoxyethyl N-oleoylsarcosinate

2-methoxyethyl N-oleoylsarcosinate

Conditions
ConditionsYield
With Amberlyst 15 acidic resin at 160℃; for 3h; Dean-Stark; Inert atmosphere;273.5 g
With Amberlyst 15 acidic resin at 160℃; for 3h; Dean-Stark; Inert atmosphere;273.5 g

110-25-8Relevant articles and documents

PRODUCTION PROCESS FOR N-ACYLAMINO ACID

-

Paragraph 0028, (2017/06/09)

PROBLEM TO BE SOLVED: To provide a production process in which a high-purity N-acylamino acid having a good color tone can be produced with high yield. SOLUTION: A production process for N-acylamino acid is provided in which an acylation reaction between an amino acid represented by formula (1) and a fatty acid chloride having a carbon number of 16 to 22 is performed in a mixed solvent between a water and an organic solvent and having an octanol/water partition coefficient of 1.6 to 3.5 under an alkali condition. (In the formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents a hydrogen atom or an alkali metal atom, and n represents an integer of 1 or 2.). SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT

Preparation of alkali metal acyl amino acids

-

, (2008/06/13)

A process of preparing alkali metal N-acyl amino acids, especially sodium N-acyl sarcosinates. The process of the invention eliminates the use of phosphorus trichloride or thionyl chloride and carboxylic acid chlorides. The process involves reacting the alkali metal N-acyl amino acid directly with a fatty acid at elevated temperatures with constant removal of water generated in the reaction.

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