Cas 110077-63-9,IrH2((CH3)2CHI)2(P(C6H5)3)2(1+)*SbF6(1-)=(IrH2((CH3)2CHI)2(P(C6H5)3)2)SbF6

110077-63-9

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Basic information

Product Name: IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-)=(IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2)SbF₆
Synonyms: IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-)=(IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2)SbF₆
CAS NO:110077-63-9
Molecular Formula:
Molecular Weight: 1294.54
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-)=(IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2)SbF₆(CAS DataBase Reference)
NIST Chemistry Reference: IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-)=(IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2)SbF₆(110077-63-9)
EPA Substance Registry System: IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-)=(IrH₂((CH₃)2CHI)2(P(C₆H₅)3)2)SbF₆(110077-63-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 110077-63-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 110077-63-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,0,0,7 and 7 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 110077-63:
(8*1)+(7*1)+(6*0)+(5*0)+(4*7)+(3*7)+(2*6)+(1*3)=79
79 % 10 = 9
So 110077-63-9 is a valid CAS Registry Number.

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110077-63-9Relevant academic research and scientific papers

Coordination chemistry of methyl iodide

Burk, Mark J.,Segmuller, Brigitte,Crabtree, Robert H.

, p. 2241 - 2246 (1987)

The complex [IrH2(IMe)2(PPh3)2]SbF6 (1) contains two iodomethane groups coordinated via the iodine atoms. The Ir-I-C angles are 105.5 (4) and 108.2 (5)°. The coordinated iodomethane is activated toward nucleophilic attack at the carbon atom by NEt3, the rate of which is enhanced by 104-105-fold relative to free MeI. Removing the hydride ligands with t-BuCH=CH2 leads to oxidative addition to give [MeIr(μ-I)(PPh3)2]2 (2). Crystal structures of 1 and 2 were determined.

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