Organometallics p. 2241 - 2246 (1987)
Update date:2022-07-30
Topics:
Burk, Mark J.
Segmuller, Brigitte
Crabtree, Robert H.
The complex [IrH2(IMe)2(PPh3)2]SbF6 (1) contains two iodomethane groups coordinated via the iodine atoms. The Ir-I-C angles are 105.5 (4) and 108.2 (5)°. The coordinated iodomethane is activated toward nucleophilic attack at the carbon atom by NEt3, the rate of which is enhanced by 104-105-fold relative to free MeI. Removing the hydride ligands with t-BuCH=CH2 leads to oxidative addition to give [MeIr(μ-I)(PPh3)2]2 (2). Crystal structures of 1 and 2 were determined.
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Doi:10.1007/BF00900987
(1958)Doi:10.1002/anie.200803842
(2008)Doi:10.1021/om000606w
(2000)Doi:10.1021/jo00231a040
(1987)Doi:10.1021/jm500522y
(2014)Doi:10.1016/S0040-4039(00)99086-5
(1989)
