Organometallics p. 2241 - 2246 (1987)
Update date:2022-07-30
Topics:
Burk, Mark J.
Segmuller, Brigitte
Crabtree, Robert H.
The complex [IrH2(IMe)2(PPh3)2]SbF6 (1) contains two iodomethane groups coordinated via the iodine atoms. The Ir-I-C angles are 105.5 (4) and 108.2 (5)°. The coordinated iodomethane is activated toward nucleophilic attack at the carbon atom by NEt3, the rate of which is enhanced by 104-105-fold relative to free MeI. Removing the hydride ligands with t-BuCH=CH2 leads to oxidative addition to give [MeIr(μ-I)(PPh3)2]2 (2). Crystal structures of 1 and 2 were determined.
View MoreBeijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)
Contact:010-52876516
Address:tongzhoubeiyuan
website:http://www.weichichem.com
Contact:+8613912949432
Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Contact:+1 (647) 918 5848
Address:2343 BRIMLEY RD., Suite 250
Wuhan Hanye Chemical New Material Co.,Ltd
Contact:+86-27-85308141
Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Naturalin Bio-Resource Co., Ltd
website:http://www.naturalin.com
Contact:+86-0731-84430651
Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.
Doi:10.1007/BF00900987
(1958)Doi:10.1002/anie.200803842
(2008)Doi:10.1021/om000606w
(2000)Doi:10.1021/jo00231a040
(1987)Doi:10.1021/jm500522y
(2014)Doi:10.1016/S0040-4039(00)99086-5
(1989)
