110137-65-0

Basic information

• Product Name: Acetamide, N-[4-[(phenylmethyl)amino]phenyl]-
• CAS NO: 110137-65-0
• Molecular Formula: C15H16N2O
• Molecular Weight: 240.305
• Mol File: 110137-65-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Acetamide, N-[4-[(phenylmethyl)amino]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-[4-[(phenylmethyl)amino]phenyl]-(110137-65-0)
• EPA Substance Registry System: Acetamide, N-[4-[(phenylmethyl)amino]phenyl]-(110137-65-0)

Safety Data

• Hazardous Substances Data: 110137-65-0(Hazardous Substances Data)

Upstream product

• 539-03-7 N-(4-chlorophenyl)acetamide 
• 100-46-9 benzylamine 
• 100-01-6 4-nitro-aniline 
• 100-44-7 benzyl chloride 
• 14309-92-3 N-benzyl-4-nitroaniline 
• 32746-39-7 (E)-N-(4-(benzylideneamino)phenyl)acetamide 
• 122-80-5 N-acetyl-p-phenylenediamine 
• 32746-39-7 acetic acid-(4-benzylidenamino-anilide) 
• 100-42-5 styrene 
• 17272-83-2 N¹-benzyl-benzene-1,4-diamine 

Relevant articles and documents

Porous polymeric ligand promoted copper-catalyzed C-N coupling of (hetero)aryl chlorides under visible-light irradiation

A porous polymeric ligand (PPL) has been synthesized and complexed with copper to generate a heterogeneous catalyst (Cu@PPL) that has facilitated the efficient C-N coupling with various (hetero)aryl chlorides under mild conditions of visible-light irradiation at 80 °C (58 examples, up to 99% yields). This method could be applied to both aqueous ammonia and substituted amines, and is compatible to a variety of functional groups and heterocycles, as well as allows tandem C-N couplings with conjunctive dihalides. Furthermore, the heterogeneous characteristic of Cu@PPL has enabled a straightforward catalyst separation in multiple times of recycling with negligible catalytic efficiency loss by simple filtration, affording reaction mixtures containing less than 1 ppm of Cu residue. [Figure not available: see fulltext.]

CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines

A class of oxalic diamides are found to be effective ligands for promoting CuI-catalyzed aryl amination with less reactive (hetero)aryl chlorides. The reaction proceeds at 120 °C with K3PO4 as the base in DMSO to afford a wide range of (hetero)aryl amines in good to excellent yields. The bis(N-aryl) substituted oxalamides are superior ligands to N-aryl-N′-alkyl substituted or bis(N-alkyl) substituted oxalamides. Both the electronic nature and the steric property of the aromatic rings in ligands are important for their efficiency.

Selective Reduction of Imines with the Diborane-Methanol System

The selective reduction of imines with diborane-methanol system was investigated.This system reduced imines quatitatively, and other functional groups tested were unaffected.Keywords-imine; diborane; selective reduction; diborane-methanol system; secondary amine; dimethoxyborane