32746-39-7

Upstream product

• 100-52-7 benzaldehyde 
• 122-80-5 N-acetyl-p-phenylenediamine 
• 104-04-1 N-(4-Nitrophenyl)acetamide 
• 100-51-6 benzyl alcohol 

Downstream Products

• 110137-65-0 N-<4-<(phenylamethyl)amino>phenyl>acetamide 
• 138432-77-6 N-(2,4-diphenyl-6-quinolinyl)acetamide 
• 138409-87-7 N-(1,2,3,4-tetrahydrp-2,4-diphenyl-6-quinolinyl)acetamide 
• 103912-24-9 [3-(4-Acetylamino-phenyl)-4-oxo-2-phenyl-thiazolidin-5-yl]-acetic acid 

Relevant academic research and scientific papers

Recyclable palladium catalyst for facile synthesis of imines from benzyl alcohols and nitroarenes

Using a supported palladium catalytic system, the reaction of nitroarenes with benzyl alcohols occurred smoothly via hydrogen transfer to produce imines in an atom-economical manner. The palladium species were dispersed well on hydrotalcite (HT) support and palladium nanoparticles with size of about 3.5 nm were formed during reaction. Both of the small size of palladium nanoparticles and the rich hydroxyl groups on HT surface enhanced the catalytic performance of Pd/HT. The catalytic system is recyclable and amenable to a variety of aromatic alcohols and nitro compounds.

Retraction: Harnessing Thiol as a Benzyl Reagent for Photocatalytic Reductive Benzylation of Imines (Organic Letters DOI: 10.1021/2Facs.orglett.0c00065)

The authors retract this article after finding in subsequent studies that the quality of the purchased catalysts has a notable impact on the reproducibility of the results. Accordingly, the authors note that additional work is necessary to understand the

Photochemically Promoted Aza-Diels-Alder-Type Reaction: High Catalytic Activity of the Cr(III)/Bipyridine Complex Enhanced by Visible Light Irradiation

Aza-Diels-Alder-type cycloaddition reactions between a range of N-arylimines and functionalized alkenes were effectively catalyzed by the Cr(III)/bipyridine complex under irradiation of blue light, to give the corresponding 1,2,3,4-tetrahydroquinoline derivatives in high yields with excellent diastereoselectivity. Typically, the reaction of benzylideneaniline with 1-vinyl-2-pyrrolidinone proceeded smoothly with a substrate-to-catalyst molar ratio (S/C) of 1000 and completed within 4 h at room temperature (20-25 °C), affording the cycloaddition product in 97% yield.