110170-23-5Relevant academic research and scientific papers
ADDITION D'ORGANOCUPRATES AUX OXAZOLIDINES CHIRALES α-β ETHYLENIQUES : II -NATURE DES INTERMEDIAIRES, MECANISME ET STEREOCHIMIE
Berlan, J.,Besace, Y.
, p. 4767 - 4776 (1986)
The addition of cuprates to α-β ethylenic oxazolidines leads to new organo-copper intermediate species.From the highly versatile course of the reaction it can be concluded that the first step is an unexpected 1-2 addition of the cuprate to the double bond.
ADDITION DIASTEREOSELECTIVE SUR UNE DOUBLE LIAISON EN α D'UNE OXAZOLIDINE CHIRALE
Huche, M.,Aubouet, J.,Pourcelot, G.,Berlan, J.
, p. 585 - 586 (2007/10/02)
Methyl copper reacts with the 2(-)R oxazolidine (93percent optically pure) obtained from cinnamaldehyde and 1-ephedrine and leads to S(+)3-phenyl butanal with an enentiomeric excess of 35percent.
