110317-58-3Relevant academic research and scientific papers
γ-Cyclodextrin as a Catalyst for the Synthesis of 2-Methyl-3,5-diarylisoxazolidines in Water
Floresta, Giuseppe,Talotta, Carmen,Gaeta, Carmine,De Rosa, Margherita,Chiacchio, Ugo,Neri, Placido,Rescifina, Antonio
, p. 4631 - 4639 (2017)
A green and efficient 1,3-dipolar cycloaddition of nitrones with different styrenes and cinnamates using a catalytic amount of γ-cyclodextrin (γ-CD) in water has been developed to give substituted isoxazolidines. γ-CD was found to be highly efficacious in
Cucurbit[7]uril as a catalytic nanoreactor for one-pot synthesis of isoxazolidines in water
Floresta, Giuseppe,Gentile, Davide,Mineo, Placido G.,Nicosia, Angelo,Patamia, Vincenzo,Rescifina, Antonio
, p. 1194 - 1203 (2020/02/22)
The main objective of supramolecular chemistry is to mimic the macrosystems present in nature, a goal that fits perfectly with the green chemistry guidelines. The aim of our work is to use the hydrophobic cavity of cucurbit[7]uril (CB[7]) to mimic nature
Ru-catalyzed rearrangement of N-methyl isoxazolidines to N-H 1,3-oxazinanes: A strategy of self-hydride transferring cleavage of N-O bonds
Yao, Chuan-Zhi,Xiao, Zu-Feng,Liu, Jie,Ning, Xiao-Shan,Kang, Yan-Biao
supporting information, p. 2498 - 2501 (2014/05/20)
A strategy of ruthenium-catalyzed self-hydride transferring cleavage of N-O bonds was designed and utilized in a cascade 1,3-dipolar cyclization of alkenes and N-methyl nitrones followed by an N-demethylative rearrangement, furnishing synthetically useful N-H 1,3-oxazinanes.
Ring-opening of isoxazolidine nucleus: Competitive formation of α,β-enones and tetrahydro-1,3-oxazines
Casuscelli, Franco,Chiacchio, Ugo,Rescifina, Antonio,Romeo, Roberto,Romeo, Giovanni,Tommasini, Silvana,Uccella, Nicola
, p. 2979 - 2990 (2007/10/02)
Treatment of isoxazolidine derivatives with methyl iodide, followed by simple heating with aqueous NaOH, gives rise to a competitive formation of α,β-enones and tetrahydro-1,3-oxazines. The ring-opening process is controlled by the stereochemistry of H5 which represents the driving factor of two competitive reaction routes.
Optically Active Tricarbonyl(η6-O-trimethylsilylbenzaldehyde)chromium(0) Complexes in Organic Synthesis: a Highly Diastereoselective 1,3-Dipolar Cycloaddition with Electron-rich Olefins
Mukai, Chisato,Kim, In Jong,Cho, Won Jea,Kido, Masaru,Hanaoka, Miyoji
, p. 2495 - 2504 (2007/10/02)
Heating of a racemic nitrone 2, derived from tricarbonyl(η6-O-trimethylsilylbenzadehyde)chromium(0) complex 1, with electron-rich olefins gave after decomplexation the cis-3,5-disubstituted isoxazolidines in a highly stereo- and regio-selective
Tricarbonyl(benzaldehyde)chromium(0) complexes in organic synthesis: A highly stereoselective 1,3-dipolar cycloaddition of chromium(0)-complexed nitrones
Mukai, Chisato,Cho, Won Jea,Kim, In Jong,Hanaoka, Miyoji
, p. 6893 - 6896 (2007/10/02)
The 1,3-dipolar cycloaddition of chromium(0)-complexed nitrones (10, 11) with electron-rich olefins (2) provided, after decomplexation with CAN, cis-3,5-disubstituted isoxazolidines (cis-14, 15) in a highly stereoselective as well as regioselective manner
