110339-29-2Relevant academic research and scientific papers
The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complex
Mukherjee, Paramita,Widenhoefer, Ross A.
supporting information, p. 3437 - 3444 (2013/07/05)
A 1:1 mixture of [AuCl(IPr)] (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2- ylidine) and AgClO4 catalyzes the intermolecular dehydrative alkoxylation of primary and secondary allylic alcohols with aliphatic primary and secondary alcohols to for
Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols
Li, Zhanjie,Parr, Brendan T.,Davies, Huw M. L.
supporting information; experimental part, p. 10942 - 10946 (2012/08/07)
The tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor rhodium carbenoids and chiral allyl alcohols is a convergent C-C bond forming process, which generates two vicinal stereogenic centers. Any of the four possible stereoisomers can be selectively synthesized by appropriate combination of the chiral catalyst Rh2(DOSP)4 and the chiral alcohol.
A Route to Key Fragments of Mycoticin B and Amphotericin B from (S)-O-Benzylglycidol
Takano, Seiichi,Shimazaki, Youichi,Sekiguchi, Yoshinori,Ogasawara, Kunio
, p. 2041 - 2044 (2007/10/02)
A concise enantioselective synthesis of C27-34 fragment of mycoticin B and C31-37 fragment of amphotericin B is described using a common building block prepared from (S)-O-benzylglycidol.
A Simple Preparation of Five-Carbon Chiral Allylic and Homoallylic Alcohol Synthons
Takano, Seiichi,Sekiguchi, Yoshinori,Sato, Nobuaki,Ogasawara, Kunio
, p. 139 - 141 (2007/10/02)
Five-carbon homoallylic and allylic alcohols 4, 5, and 6, potentially useful building blocks for the syntheses of a wide variety of optically active compounds, are prepared from chiral (S)-O-benzylglycidol (1) via the selective formation of the terminal a
Versatile Chiral Building Blocks bearing a Secondary Methyl Group from (S)-O-benzylglycidol (Benzyloxymethyloxirane)
Takano, Seiichi,Sekiguchi, Yoshinori,Ogasawara, Kunio
, p. 555 - 557 (2007/10/02)
Versatile chiral building blocks for the construction of chiral natural products bearing a secondary methyl group have been efficiently prepared from (S)-O-benzylglycidol.
