111149-37-2

Upstream product

• 111149-31-6 (3R,4S)-(E)-7-benzyloxy-4-methyl-1-trimethylsilylhept-5-en-1-yn-3-ol 
• 120448-41-1 (3R,4S)-(E)-7-benzyloxy-4-methylhept-5-en-1-yn-3-ol 
• 141207-20-7 Benzoic acid (E)-(1S,2S)-5-benzyloxy-1-ethynyl-2-methyl-pent-3-enyl ester 
• 123372-87-2 (3S,4S)-(E)-7-benzyloxy-4-methylhept-5-en-1-yn-3-ol 
• 111149-29-2 (R)-(Z)-1-benzyloxy-2-(3'-trimethylsilylpropargyloxy)-3-pentene 
• 120448-40-0 (R)-(Z)-1-benzyloxy-2-propargyloxy-3-pentene 
• 110339-29-2 (R)-(Z)-1-Benzyloxy-2-hydroxy-3-pentene 
• 111149-36-1 (4R,5R)-2-Benzyloxymethyl-3-bromo-5-ethynyl-4-methyl-tetrahydro-furan 
• 111149-36-1 (4R,5S)-2-Benzyloxymethyl-3-bromo-5-ethynyl-4-methyl-tetrahydro-furan 
• 111149-36-1 (2S,3S,4RS,5RS)-5-benzyloxymethyl-4-bromo-2-ethynyl-3-methyltetrahydrofuran 
• 111149-36-1 (2R,3S,4RS,5RS)-5-benzyloxymethyl-4-bromo-2-ethynyl-3-methyltetrahydrofuran 

Downstream Products

• 111149-40-7 (3R,4S)-(E)-7-benzyloxy-4-methylhept-5-en-3-ol 
• 111149-38-3 (3S,4S)-(E)-7-benzyloxy-4-methylhept-5-en-3-ol 
• 141858-95-9 (3R,4S)-(E)-7-benzyloxymethoxy-3-tert-butyldimethylsilyloxy-4-methyl-hept-5-ene 
• 141858-86-8 (4S,5R)-(E)-1-benzyloxy-5-tert-butyldimethylsilyloxy-4-methyl-2-heptene 
• 103563-54-8 (3R,4S)-(E)-7-<(benzyloxy)methoxy>-4-methyl-5-hepten-3-ol 
• 124732-42-9 (4S,5S)-(E)-1-benzyloxy-5-tert-butyldimethylsilyloxy-4-methyl-2-heptene 
• 111149-39-4 Benzoic acid (E)-(1R,2S)-5-benzyloxy-1-ethyl-2-methyl-pent-3-enyl ester 

Relevant academic research and scientific papers

AN ENANTIOCONTROLLED ROUTE TO PROTOMYCINOLIDE IV AND ITS PRESUMED BIOGENETIC PRECURSORS USING (S)-O-BENZYLGLYCIDOL

Starting with (S)-O-benzylglycidol (9) as only chiral building block, a formal synthesis of protomycinolide IV (1) and the first syntheses of its presumed biogenetic precursors methyl epimycinonate I (2), methyl mycinonate I (3), methyl mycinonate II (4),

STEREOCHEMISTRY OF THE PROPOSED INTERMEDIATES IN THE BIOSYNTHESIS OF MYCINAMICINS

Stereochemistry of the proposed intermediates in the biosynthesis of mycinamicins isolated from the culture filtrate of Micromonospora griseorubida sp. has been established.

Versatile Chiral Building Blocks bearing a Secondary Methyl Group from (S)-O-benzylglycidol (Benzyloxymethyloxirane)

Versatile chiral building blocks for the construction of chiral natural products bearing a secondary methyl group have been efficiently prepared from (S)-O-benzylglycidol.