110379-08-3

Basic information

• Product Name: 2-methyl-2-phenyl-1,3-dithiolane 1-oxide
• Synonyms: 2-methyl-2-phenyl-1,3-dithiolane 1-oxide
• CAS NO: 110379-08-3
• Molecular Weight: 212.337
• Mol File: 110379-08-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-methyl-2-phenyl-1,3-dithiolane 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-2-phenyl-1,3-dithiolane 1-oxide(110379-08-3)
• EPA Substance Registry System: 2-methyl-2-phenyl-1,3-dithiolane 1-oxide(110379-08-3)

Safety Data

• Hazardous Substances Data: 110379-08-3(Hazardous Substances Data)

Upstream product

• 5769-02-8 2-methyl-2-phenyl[1,3]dithiolane 

Downstream Products

• 113475-91-5 (1-Ethenesulfonyl-1-methylsulfanyl-ethyl)-benzene 
• 84065-85-0 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-phenylvinyl)ester 
• 79403-80-8 n-butyl (+/-)-sec-phenylethyl thioether 
• 18624-64-1 <1-(Methylthio)ethenyl>benzene 
• 84065-89-4 2-Methyl-2-phenyl-1,3-dithiolan-1,1-dioxid 
• 128827-91-8 2-Methyl-2-phenyl-[1,3]dithiole 
• 35756-26-4 2,3-dihydro-5-phenyl-1,4-dithiin 

Relevant articles and documents

Reactions of 1,3-Dithiolane with Nucleophiles

Reaction of benzenethiol with the 1,3-dithiolane 1,3-dioxides 3a-f gave the 1,4-dithiane 1-oxides 4-5, the α,β-unsaturated sulfoxides 6-9, the ring-opening products 10-11 and various reduction products.Addition of benzenethiol, malononitrile, diethyl malo

PHOTOSENSITIZED ELECTRON TRANSFER OXIDATION OF 2-SUBSTITUTED 1,3-DITHIOLANE TO 1,3-DITHIOLANE-1-OXIDE

Irradation of a solution of 1,3-dithiolane, 1-cyanonaphthalene in O2-saturated CH3CN:H2O (3:1) at 350 nm furnishes good yields of 1,3-dithiolane-1-oxide.

ASYMMETRIC OXIDATION OF 1,3-DITHIOLANES. A ROUTE TO THE OPTICAL RESOLUTION OF CARBONYL COMPOUNDS

The asymmetric oxidation (t-BuO2H, Ti(OPr-i)4, DET) of a series of 1,3-dithiolanes was carried out to produce the corresponding S-oxides with high chemical and optical yields.By contrast, the oxidation of 1,3-dithianes and 1,3-oxathiolane prepared from the same carbonyl compounds gave much lower optical yields.The optical resolution of the model ketone, dl-menthone, via a) 1,3-dithiolane formation b) asymmetric S-oxidation c) chromatographic diasteromeric separation d) regeneration of the carbonyl group, (93percent optical yield), is described.