5769-02-8Relevant articles and documents
Crystallinity after decarboxylation of a metal-carboxylate framework: indestructible porosity for catalysis
Cheng, Shengxian,Feng, Weijin,Gao, Wenpei,He, Jun,Hu, Jieying,Pan, Xiaoqing,Tieu, Peter,Xu, Zhengtao
, p. 11902 - 11910 (2020/09/21)
We report a curious case study of a Zr(iv)-carboxylate framework, which retains significant crystalline order after cascade thermocyclization of its linker components, and - more notably - after the crucial carboxylate links were severed by heat. Vigorous heat treatment (e.g., 450 °C and above) benzannulates the multiple alkyne groups on the linker to generate linked nanographene blocks and to afford real stability. The resultant Zr oxide/nanographene hybrid solid is stable in saturated NaOH and concentrated H3PO4, allowing a convenient anchoring of H3PO4into its porous matrix to enable size-selective heterogeneous acid catalysis. The Zr oxide components can also be removed by strong hydrofluoric acid to further enhance the surface area (up to 650 m2g?1), without collapsing the nanographene scaffold. The crystallinity order and the extensive thermal transformations were characterized by X-ray diffraction, scanning transmission electron microscopy (STEM), IR, solid state NMR and other instrumental methods.
Sulfonated polyanthracene-catalyzed highly efficient and chemoselective thioacetalization of carbonyl compounds and transthioacetalization of acetals and acylals
Fahid,Pourmousavi
, p. 16 - 29 (2015/10/20)
A straightforward and highly efficient procedure for the thioacetalization of a variety of aldehydes and transthioacetalization of acylals and acetals in good to excellent yields using catalytic amounts of sulfonated polyanthracene (S-PAT) is reported. Th
Efficient thioacetalisation of carbonyl compounds
Habibi, Davood,Rahmani, Payam,Akbaripanah, Ziba
, p. 417 - 421 (2014/01/06)
The thioacetalisation of a variety of heterocyclic, aromatic, and aliphatic carbonyl compounds (1 mmol) with ethane-1,2-dithiol (1 mmol) using silica sulphuric acid (SSA) is presented as an efficient heterogeneous catalyst under mild and solvent-free cond