110383-80-7

Upstream product

• 10548-46-6 1,6-anhydro-2,3,4-tri-O-benzyl-β-D-glucopyranose 
• 75-77-4 chloro-trimethyl-silane 
• 53810-61-0 methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 38184-15-5 methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1<*>6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 78687-40-8 methyl 2,3,4-tri-O-benzyl-6-O-(trimethylsilyl)-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 110383-77-2 2,3,4-tri-O-benzyl-6-O-trimethylsilyl-α-D-glucopyranosyl bromide 

Downstream Products

• 174193-85-2 Acetic acid (2S,3R,4S,6S)-6-acetoxymethyl-3-benzyloxy-2-[(2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

Synthesis of the methyl α-glycosides of some isomalto-oligosaccharides specifically deoxygenated at position C-4

Methyl α-isomaltoside and methyl α-isomaltotrioside specifically deoxygenated at position C-4 of various glucopyranosyl units were synthesized by condensation of either 1,6-di-O-acetyl-2,3-di-O-benzyl-4-deoxy-α,β-D-xylo-hexopyranose (7) or 1,6-di-O-acetyl

STEREOSELECTIVE SYNTHESIS OF α-D-GLUCOPYRANOSIDES VIA 6-SILYL-α-D-GLUCOPYRANOSYL BROMIDES

Bromotrimethylsilane cleaved 2,3,4-tri-O-benzyl-1,6-anhydro-β-D-glucopyranose (1) to give 2,3,4-tri-O-benzyl-6-O-trimethylsilyl-α-D-glucopyranosyl bromide (2).Reaction of 2 with ROH/diisopropylethylamine gave the corresponding α-glucopyranosides.