1105107-47-8

Basic information

• Product Name: (Z)-1-phenyl-3,3,3-trifluoro-1-trimethylsiloxypropene
• CAS NO: 1105107-47-8
• Molecular Weight: 260.331
• Mol File: 1105107-47-8.mol

Chemical Properties

• CAS DataBase Reference: (Z)-1-phenyl-3,3,3-trifluoro-1-trimethylsiloxypropene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-phenyl-3,3,3-trifluoro-1-trimethylsiloxypropene(1105107-47-8)
• EPA Substance Registry System: (Z)-1-phenyl-3,3,3-trifluoro-1-trimethylsiloxypropene(1105107-47-8)

Safety Data

• Hazardous Substances Data: 1105107-47-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 2267-65-4 phenyl 1,2,2,2,-tetrafluoroethyl ketone 

Relevant articles and documents

Reductive modification of difluoromethylene moiety in pentafluoropropionyl group

The reductive Mg-promoted defluorinative-silylation of 2,2,3,3,3-pentafluoropropiophenone readily produces the α-trifluoromethyl enol silyl ether, which then react with electrophiles to give a variety of 2-substituted-3,3,3-trifluoropropiophenones in excellent yields. The same protocol is applicable for the preparation of enol silyl ether of 3,3,3-trifluoropropiophenone. Fluoride ion catalyzed 1,2-desilylative-defluorination of 2,3,3,3-tetrafluoro-2-trimethylsilyloxypropiophenone provided 3,3,3-trifluoro-1-phenyl-1,2-propanedione in a good yield.