2267-65-4Relevant articles and documents
NUCLEOPHILIC REACTIONS OF FLUOROOLEFINS. II. REGIOSELECTIVITY AND ELIMINATION-ADDITION COMPETITION IN THE REACTION OF 1-PHENYLPENTAFLUOROPROPENES WITH SODIUM ETHOXIDE
Dmowski, Wojciech
, p. 201 - 220 (1982)
1-Phenylpentafluoropropene and its para-substituted analogs 1 are susceptible to nucleophilic attack at both vinylic carbon atoms C-1 and C-2.They react with ethanolic sodium ethoxide to give predominantly substitution products, 1-ethoxy-1-phenyltetrafluo
Dephosphorylation of 1-Substituted F-1-Alkenyl Phosphates with Diisobutylaluminium Hydride. A New Highly Efficient Method for Generating F-Alkyl Ketone Aluminium(III) Enolates
Ishihara, Takashi,Yamaguchi, Koichi,Kuroboshi, Manabu
, p. 1191 - 1194 (2007/10/02)
1-Substituted F-1-alkenyl phosphates, prepared easily from F-alkyl ketones, were treated with diisobutylaluminium hydride in tetrahydrofuran at 0 deg C for 5 min or at room temperature for 30 min to generate quantitetively the corresponding ketone alumini