110522-67-3

Upstream product

• 100-44-7 benzyl chloride 
• 110522-66-2 (2S,3S,4S,5S)-2,5-Bis-benzyloxy-1,6-bis-trityloxy-hexane-3,4-diol 
• 488-45-9 L-iditol 
• 20513-98-8 1,2-O-isopropylidene-α-D-glucofuranurono-6,3-lactone 
• 55263-78-0 1,2-O-isopropylidene-5-O-tosyl-α-D-glucuronolactone 
• 30694-75-8 Toluene-4-sulfonic acid (3aR,3bS,6R,6aS,7aR)-5-hydroxy-2,2-dimethyl-hexahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-6-yl ester 
• 94926-00-8 2,5-di-O-benzyl-L-iditol 
• 114343-01-0 (3aR,3bS,5S,6S,6aR,7aR)-5-Methoxy-2,2-dimethyl-hexahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-6-ol 
• 114343-02-1 (2S,3S,3aR,5S,6R,6aR)-2,5-Dimethoxy-hexahydro-furo[3,2-b]furan-3,6-diol 
• 487-44-5 D-(+)-glucuronic acid γ-lactone 
• 76-83-5 trityl chloride 
• 100-39-0 benzyl bromide 
• 159346-83-5 1,6-di-O-triphenylmethyl-L-iditol 

Downstream Products

• 62102-45-8 2,3,4,5-tetra-O-benzyl-L-iditol 
• 62102-44-7 2,3,4,5-tetra-O-benzyl-D-ido-hexodialdose 

Relevant academic research and scientific papers

Samarium diiodide-mediated synthesis of D-3,4,5,6-tetra-O-benzyl-myo-inositol

The preparation of D-3,4,5,6-tetra-O-benzyl-myo-inositol in 5 steps from L-iditol is described, the cyclization step being a dialdehyde reductive coupling mediated by SmI2.

Synthesis of Optically Active Inositol Derivatives Starting from D-Glucurono-6,3-lactone

D-Glucurono-6,3-lactone was converted to optically active and partially protected inositols.The synthetic strategy involves an efficient conversion of the D-gluco configuration to the L-ido configuration and dials to cyclitols.