62102-44-7Relevant academic research and scientific papers
N-heterocyclic carbene-catalyzed benzoin strategy for divergent synthesis of cyclitol derivatives from alditols
Kang, Bubwoong,Sutou, Toshiaki,Wang, Yinli,Kuwano, Satoru,Yamaoka, Yousuke,Takasu, Kiyosei,Yamada, Ken-Ichi
, p. 131 - 147 (2015/01/30)
A divergent synthesis of cyclitol derivatives has been developed utilizing an N-heterocyclic carbene-catalyzed benzoin-type cyclization of C2-symmetrical dialdoses. The resulting inososes are versatile intermediates, which are readily converted
Synthesis of differentially protected myo- and chiro-inositols from D-xylose: Stereoselectivity in intramolecular SmI2-promoted pinacol reactions
Luchetti, Giovanni,Ding, Kejia,Kornienko, Alexander,D'Alarcao, Marc
scheme or table, p. 3148 - 3154 (2009/04/07)
Methods for the enantioselective conversion of D-xylose into differentially protected myo-inositol and L-chiro-inositol have been developed. The key transformation is a highly diastereoselective intramolecular SmI 2-promoted pinacol coupling. T
Syntheses of tetrahydroxyazepanes from chiro-inositols and their evaluation as glycosidase inhibitors
Painter, Gavin F.,Eldridge, Paul J.,Falshaw, Andrew
, p. 225 - 232 (2007/10/03)
Two pairs of C2-symmetric tetrahydroxyazepanes [(-), (+)-1 and (-), (+)-2] have been synthesized from the enantiomeric chiro-inositols and evaluated as glycosidase inhibitors. Alternative syntheses of ido-tetrahydroxyazepanes (-)- and (+)-2 fro
Samarium diiodide-mediated synthesis of D-3,4,5,6-tetra-O-benzyl-myo-inositol
Guidot, J. P.,Gall, T. Le,Mioskowski, C.
, p. 6670 - 6672 (2007/10/02)
The preparation of D-3,4,5,6-tetra-O-benzyl-myo-inositol in 5 steps from L-iditol is described, the cyclization step being a dialdehyde reductive coupling mediated by SmI2.
Synthesis of Optically Active Inositol Derivatives Starting from D-Glucurono-6,3-lactone
Watanabe, Yutaka,Mitani, Motohiro,Ozaki, Shoichiro
, p. 123 - 126 (2007/10/02)
D-Glucurono-6,3-lactone was converted to optically active and partially protected inositols.The synthetic strategy involves an efficient conversion of the D-gluco configuration to the L-ido configuration and dials to cyclitols.
