110604-56-3

Upstream product

• 875247-76-0 5-cyclohexylpentan-2-one 
• 186581-53-3 diazomethane 
• 4441-67-2 4-cyclohexylbutyryl chloride 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 4441-63-8 4-cyclohexylbutanoic acid 

Downstream Products

• 1253176-35-0 1-((2S,3S)-1-(bis(4-methoxy-3,5-dimethyl-phenyl)methyl)-3-phenylaziridin-2-yl)-4-cyclohexylbutan-1-one 
• 1253176-50-9 1-((2R,3R)-1-(bis(4-methoxy-3,5-dimethyl-phenyl)methyl)-3-phenylaziridin-2-yl)-4-cyclohexylbutan-1-one 
• 1253176-36-1 1-((2S,3S)-1-(bis(4-methoxy-3,5-dimethylphenyl)methyl)-3-cyclohexylaziridin-2-yl)-4-cyclohexylbutan-1-one 
• 1253176-51-0 1-((2R,3R)-1-(bis(4-methoxy-3,5-dimethylphenyl)methyl)-3-cyclohexylaziridin-2-yl)-4-cyclohexylbutan-1-one 
• 1253176-49-6 1-((2R,3R)-1-benzhydryl-3-phenylaziridin-2-yl)-4-cyclohexylbutan-1-one 
• 1253176-34-9 1-((2S,3S)-1-benzhydryl-3-phenylaziridin-2-yl)-4-cyclohexylbutan-1-one 
• 5962-88-9 5-cyclohexylvaleric acid 
• 10264-57-0 3-cyclohexyl-1-cyclopentanone 
• 110604-53-0 4-Ethoxy-benzenesulfonic acid 5-cyclohexyl-2-oxo-pentyl ester 

Relevant academic research and scientific papers

Trimethylsilyldiazomethane as a versatile stitching agent for the introduction of aziridines into functionalized organic molecules

A highly enantioselective route for the introduction of aziridines into functionalized organic molecules was developed via a tandem acylation and aziridination of TMSCHN2.

Unusual products from dirhodium tetraacetylate-catalyzed decomposition of diazoacetylcycloalkanes

Rh2(OAc)4-assisted decompositions of diazoacetylcycloalkanes are shown to yield cycloalkylacetic acids (Wolff rearrangement), unexpected cycloalkylcarboxylic acids and bicyclic ketones (intramolecular C-H bond insertion). Rh2(OCOF3)4-promoted reactions, on the other hand, have furnished bicyclic ketones and ketene dimers.