875247-76-0Relevant academic research and scientific papers
Site-selective catalytic deaminative alkylation of unactivated olefins
Sun, Shang-Zheng,Romano, Ciro,Martin, Ruben
supporting information, p. 16197 - 16201 (2019/10/17)
A catalytic deaminative alkylation of unactivated olefins is described. The protocol is characterized by its mild conditions, wide scope - including the use of ethylene as substrate -, and exquisite site-selectivity pattern for both a-olefins and internal olefins, thus unlocking a new catalytic platform to forge sp3-sp3 linkages, even in the context of late-stage functionalization.
Trimethylsilyldiazomethane as a versatile stitching agent for the introduction of aziridines into functionalized organic molecules
Ren, Hong,Wulff, William D.
supporting information; experimental part, p. 4908 - 4911 (2011/02/21)
A highly enantioselective route for the introduction of aziridines into functionalized organic molecules was developed via a tandem acylation and aziridination of TMSCHN2.
