110731-13-0Relevant academic research and scientific papers
Intramolecular reactivity of functionalized arylcarbenes: 2-Allyloxyphenylcarbenes
Gotzhein, Frank,Kirmse, Wolfgang
, p. 1373 - 1376 (2007/10/03)
2-Allyloxyphenylcarbenes (8) undergo intramolecular addition (→ 9) and (formal) C-H insertion (→ 11) competitively. Stereochemical labels indicate that 11 and major amounts of 9 arise from triplet 8. The intermolecular O-H insertion of singlet 8 with meth
Intramolecular addition reactions of functionalized arylcarbenes to double bonds
Kirmse, Wolfgang,H?mberger, Günter
, p. 3925 - 3934 (2007/10/02)
Arylcarbenes with unsaturated ortho substituents (vinyloxy, 1-propenyloxy, allyl, 2-butenyl, 2,4-pentadienyl) were generated in methanol by photolysis of diazo precursors. Intermolecular OH insertion was found to compete with intramolecular addition to th
