11084-15-4

Basic information

• Product Name: 6-hydroxycyclohexa-1,3-dien-1-yl
• Synonyms: Cyclohexadienyl, 6-hydroxy-
• CAS NO: 11084-15-4
• Molecular Formula: C₆H₇O
• Molecular Weight: 95.1192
• Mol File: 11084-15-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 6-hydroxycyclohexa-1,3-dien-1-yl(CAS DataBase Reference)
• NIST Chemistry Reference: 6-hydroxycyclohexa-1,3-dien-1-yl(11084-15-4)
• EPA Substance Registry System: 6-hydroxycyclohexa-1,3-dien-1-yl(11084-15-4)

Safety Data

• Hazardous Substances Data: 11084-15-4(Hazardous Substances Data)

Upstream product

• 3352-57-6 hydroxyl 
• 71-43-2 benzene 
• 91114-62-4 5-hydroxy-1,3-cyclohexadiene-6-peroxyl radical 
• 131738-20-0 6-hydroxy-1,4-cyclohexadiene-3-peroxyl radical 

Downstream Products

• 71-43-2 benzene 
• 12169-67-4 cyclohexa-1->5-dienyl 
• 108-95-2 phenol 
• 131738-20-0 6-hydroxy-1,4-cyclohexadiene-3-peroxyl radical 
• 91114-62-4 5-hydroxy-1,3-cyclohexadiene-6-peroxyl radical 

Relevant articles and documents

Detailed rate coefficients and the enthalpy change of the equilibrium reaction over the temperature range 345-385 K

The reaction between OH and C6H6 in He has been studied over the pressure range 250-500 Torr and the temperature range 345-385 K by means of the laser-photolysis/laser-induced-fluorescence technique.Analysis of the temporal profile of yielded the detailed rate coefficients and the equilibrium constant for the reaction OH + C6H6 + M HOC6H6 + M.The temperature dependence of the rate coefficients for the forward, the reverse,and the adduct-loss reactions have been determined to be kf = (2.0+/-0.1)x10-14 exp cm3molecule-1 s-1, kr = (3.0+/-0.2)x1012 exp s-1, and ka = (1.7+/-0.3)x106 exp s-1, respectively.The temperature dependence of the equilibrium constant led to the enthalpy of reaction ΔH(365+/-20 K) = -(20.0+/-1.2) kcal mol-1 and the entropy of reaction ΔS(365+/-20 K) = -(33.6+/-2.5 cal K-1 mol-1, greater than previously reported values; after correction for temperature dependence, ΔH0(298 K) = -(19.9+/-1.2) kcal mol-1 and ΔS0(298 K) = -(33.4+/-2.6) cal K-1 mol-1.

Gas phase oxidation of benzene: Kinetics, thermochemistry and mechanism of initial steps

Volatile aromatic compounds participate to a significant extent to the pollution of the troposphere and to ozone formation. A new investigation of the primary steps of the benzene oxidation, involving complementary experimental and theoretical approaches,

Evidence for Hydroxyl Radicals as an Active Species Generated from Udenfriend's Reagent

The inhibitory effect of six aliphatic alcohols, which are typical OH radical scavengers, on the yield of phenol in the oxidations of benzene with Fenton's (Fe(II) + H2O2) and Udenfriend's (Fe(II) + EDTA + O2 + L-ascorbic acid) reagents has been examined.