1108747-40-5Relevant academic research and scientific papers
Hydrosilylation of aldehydes and ketones catalyzed by Nickel PCP-Pincer hydride complexes
Chakraborty, Sumit,Krause, Jeanette A.,Guan, Hairong
, p. 582 - 586 (2009)
Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of C=O bonds of aldehydes and ketones in the presence of other functional groups. The mechanism involves C=O insertion into a nickel-hydrogen bond, followed by cleavage of the new
A robust nickel catalyst for cyanomethylation of aldehydes: Activation of acetonitrile under base-free conditions
Chakraborty, Sumit,Patel, Yogi J.,Krause, Jeanette A.,Guan, Hairong
supporting information, p. 7523 - 7526 (2013/07/26)
Nick of time: The nickel cyanomethyl complex 1 catalyzes the room temperature coupling of aldehydes with acetonitrile under base-free conditions. The catalytic system is long-lived and remarkably efficient with high turnover numbers (TONs) and turnover fr
