110889-27-5

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-C-<(Z)-2-hydroxyethylidene>-2,2¹-O-isopropylidene-α-D-ribo-hexopyranoside
• Synonyms: methyl 4,6-O-benzylidene-3-C-<(Z)-2-hydroxyethylidene>-2,2¹-O-isopropylidene-α-D-ribo-hexopyranoside
• CAS NO: 110889-27-5
• Molecular Weight: 348.396
• Mol File: 110889-27-5.mol

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-C-<(Z)-2-hydroxyethylidene>-2,2¹-O-isopropylidene-α-D-ribo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-C-<(Z)-2-hydroxyethylidene>-2,2¹-O-isopropylidene-α-D-ribo-hexopyranoside(110889-27-5)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-C-<(Z)-2-hydroxyethylidene>-2,2¹-O-isopropylidene-α-D-ribo-hexopyranoside(110889-27-5)

Safety Data

• Hazardous Substances Data: 110889-27-5(Hazardous Substances Data)

Upstream product

• 116-11-0 2-Methoxypropene 
• 110889-24-2 (4aR,6S,7R,8aS)-8-[2-Hydroxy-eth-(E)-ylidene]-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 

Downstream Products

• 110889-28-6 methyl 4,6-O-benzylidene-3-C-<(S)-1,2-dihydroxyethyl>-2,2¹-O-isopropylidene-α-D-glucopyranoside 
• 110889-33-3 methyl 1¹-O-acetyl-3-C-<(S)-1,2-dihydroxyethyl>-2,2¹-O-isopropylidene-6-O-pivaloyl-4-O-p-tolylsulfonyl-α-D-glucopyranoside 
• 110889-30-0 Acetic acid (4aR,6S,6aR,11S,11aS,11bR)-11a-hydroxy-6-methoxy-8,8-dimethyl-2-phenyl-octahydro-1,3,5,7,9-pentaoxa-cyclohepta[a]naphthalen-11-yl ester 
• 110889-28-6 methyl 4,6-O-benzylidene-3-C-<(R)-1,2-dihydroxyethyl>-2,2¹-O-isopropylidene-α-D-glucopyranoside 

Relevant articles and documents

SYTHESIS OF METHYL 4-DEOXY-3-C--α-D-xylo-HEXOPYRANOSIDE AND METHYL 2,21-ANHYDRO-3-C--α-D-GLUCOPYRANOSIDE DERIVATIVES

The title branched-chain sugars possessing a new type of two-carbon branch were synthesised from D-glucose.These compounds are important intermediates for a total synthesis of the nucleoside antibiotics, amipurimycin and miharamycin.