11092-32-3 Usage
Characteristics
Aluminum Oxide (Alumina) is the most widely used oxide, chiefly because it is plentiful, relatively low in cost, and equal to or better than most oxides in mechanical properties. Density can be varied over a wide range, as can purity — down to about 90% alumina — to meet specific application requirements. Alumina ceramics are the hardest, strongest, and stiffest of the oxides. They are also outstanding in electrical resistivity, dielectric strength, are resistant to a wide variety of chemicals, and are unaffected by air, water vapor, and sulfurous atmospheres. However, with a melting point of only 2039°C, they are relatively low in refractoriness, and at 1371°C retain only about 10% of room-temperature strength. In addition to its wide use as electrical insulators and its chemical and aerospace applications, the high hardness and close dimensional tolerance capability of alumina make this ceramic suitable for such abrasion-resistant parts as textile guides, pump plungers, chute linings, discharge orifices, dies, and bearings.
Uses
Aluminum oxide is used for the separation of both inorganic anions and acidic organic molecules such as acidic amino acids, aromatic acids and carboxylic acids. It is essential in protein extraction as a component in the preparation of tissues. It is also used as a grinding or blending agent. Aluminum oxide is a source of aluminum in reactions, an abrasive agent, and as a refractory material. Also Aluminum oxide can act as a catalyst in a variety of reactions such as the claus process and in the dehydration of alcohols to alkenes. In single crystals of aluminum oxide intrinsic diffusion occurs in a high temperature region.
Preparation
Pure alumina, needed to produce aluminum by the Hall process, is made by the Bayer process. The starting material is bauxite (Al2O3 ? nH2O). The ore contains impurities, such as, SiO2, Fe2O3, TiO2, and Na2O. Most impurities are removed following treatment with caustic soda solution. Bauxite is dissolved in NaOH solution. Silica, iron oxides and other impurities are filtered out of the solution. CO2 is then bubbled through this solution. This precipitates out hydrated alumina, which is heated to remove water and produce Al2O3. These impurities are removed. Calcinations of bauxite produce alumina of abrasive and refractory grades. Activated aluminas of amorphous type, as well as the transition aluminas of γ, η, χ, and ρ forms, are obtained from various aluminum hydroxides, such as, α- and β-trihydrates, α-monohydrate and alumina gel. Such chemicals are obtained from bauxite by the Bayer process also.
Definition
A mineral form of aluminiumoxide, Al2O3. It crystallizesin the trigonal system and occurs aswell-developed hexagonal crystals. Itis colourless and transparent whenpure but the presence of other elementsgives rise to a variety ofcolours. Ruby is a red variety containingchromium; sapphire is ablue variety containing iron andtitanium. Corundum occurs as arock-forming mineral in both metamorphicand igneous rocks. It ischemically resistant to weatheringprocesses and so also occurs in alluvial(placer) deposits. The secondhardest mineral after diamond (it hasa hardness of 9 on the Mohs’ scale), itis used as an abrasive.
Hazard
Chronic inhalation of Al2O3 dusts may cause lung damage.
Agricultural Uses
Alumina is a white or colorless oxide occurring in two
forms, a-alumina and γ-alumina. The γ-alumina turns
into a stable a form on heating. Naturally occurring
alumina is called corundum or emery.
The gemstones ruby and sapphire are aluminum
oxides colored by minute traces of chromium and cobalt,
respectively. The highly protective film of oxide formed
on the surface of aluminum is yet another structural
variation, a defective form of rock salt.
Pure aluminum oxide is obtained by dissolving
bauxite ore in sodium hydroxide solution to eliminate
insoluble impurities. Seeding the solution with material
from a previous batch precipitates the hydrated oxide,
which on further heating gives γ-alumina at 500 to 800°C
and pure a-alumina at 1150 to 1200°C. The latter is one
of the hardest materials known. It is used widely as an
abrasive substance in both its natural and synthetic forms.
Its refractory nature makes alumina bricks an ideal
material for furnace linings and high temperature
cements.
Alumina occurs in phosphate rocks along with iron
and other impurities in small percentages. Alumina and
iron in phosphate rock make the superphosphate moist
and sticky. The maximum acceptable alumina and iron in
the rock for farming is 3 to 4 %
Materials Uses
Fused aluminum oxide was the second synthetic abrasive to be developed. Synthetic aluminum oxide (alumina) is made as a white powder and can be somewhat harder than corundum (natural alumina) because of its purity. However, corundum has a Mohs hardness of approximately 9 (on a scale of 1 to 10. Alumina can be processed with different properties by slight alteration of the reactants in the manufacturing process. Several grain sizes of alumina are available, and alumina has largely replaced emery for several abrasive uses. Aluminum oxide is widely used to make bonded abrasives, coated abrasives, and air-propelled grit abrasives for dental applications.
Sintered aluminum oxide is used to make white stones, which are popular for adjusting dental enamel and finishing metal alloys, resin-based composites, and ceramic materials.
Pink and ruby variations of aluminum oxide abrasives are made by adding chromium compounds to the original melt. These variations are sold in a vitreous-bonded form as noncontaminating mounted stones for the preparation of metal– ceramic alloys to receive porcelain. Remnants of these abrasives and other debris should be removed from the surface of metals used for metal–ceramic bonding so as not to prevent optimal bonding of porcelain to the metal alloy. A review by Yamamoto (see Selected Reading) suggests that carbide burs are the most effective instruments for finishing this type of alloy because they do not contaminate the metal surface with entrapped abrasive particles.
CORUNDUM: This mineral form of aluminum oxide is usually white. Its physical properties are inferior to those of manufactured alpha (α) aluminum oxide (Al2O3), which has largely replaced corundum in dental applications. Corundum is used primarily for grinding metal alloys and is available as a bonded abrasive in several shapes. It is most commonly used in an instrument known as a white stone.
Check Digit Verification of cas no
The CAS Registry Mumber 11092-32-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,1,0,9 and 2 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 11092-32:
(7*1)+(6*1)+(5*0)+(4*9)+(3*2)+(2*3)+(1*2)=63
63 % 10 = 3
So 11092-32-3 is a valid CAS Registry Number.
InChI:InChI=1/2Al.3O/q2*+3;3*-2
11092-32-3Relevant articles and documents
Experimental and Transition-State Theory Studies of the Gas-Phase Reactions of AlCl with N2O, CO2, and SO2
Futerko, Peter M.,Fontijn, Arthur
, p. 7222 - 7227 (1993)
The high-temperature fast-flow reactor technique has been used to make kinetic measurements.A weighted fit to the AlCl + N2O data gives k(700-990 K) = 5.6 x 10-11 exp(-7380 K/T) cm3 molecule-1 s-1.A weighted fit to the AlCl + CO2 measurements leads to the expression k(900-1790 K) = 4.4 x 10-23 (T/K) -14 K/T) cm3 molecule-1 s-1. 2? accuracy limits are about +/- 25percent.An upper limit k(800-1100 K) -14 cm3 molecule-1 s-1 has been determined for the AlCl + SO2 reaction.An alternate form of classical transition-state theory is developed to allow predictions on the preexponential part of rate coefficient expressions for metallic species.This model-based transition-state-theory (MTSZ) method used a valence-force molecular model to estimate rotational constants and vibrational frequencies of the transition state and is applicable to reactions with early barriers, typical of many exothermic charge-transfer reactions.The geometrical parameters and force constants that describe the molecular model are derived from properties of the reactants.For the N2O reaction good agreement between MTST and experiment is obtained, based on the assumption of an O atom abstraction reaction leading to OAlCl.No such agreement is found for the CO2 reaction, which indicates adduct formation as the main AlCl consumption channel.For the previously measured AlCl + O2 reaction MTST calculations suggest that abstraction can be some significance above 1500 K; however, adduct formation appears to dominate over most of the 490-1750 K range.
The molecules AlO2, Al(O2)2, and Al(O 2)3: Experimental and quantum-chemical investigations on the oxidation of aluminum atoms
Stoesser, Gregor,Schnoeckel, Hansgeorg
, p. 4261 - 4264 (2005)
(Chemical Equation Presented) On the route to alumina, oxygen-rich oxides such as Al(O2)3 (see picture) are detected spectroscopically during the stepwise oxidation of aluminum atoms and confirmed structurally by quantum-chemical cal
A High-Temperature Fast-Flow-Reactor Kinetics Study of the Reaction AlO + CO2 -> AlO2 + CO. Thermochemical Implications
Rogowski, Donald F.,English, Andrew J.,Fontijn, Arthur
, p. 1688 - 1691 (1986)
The title reaction has been studied in a high-temperature fast-flow reactor (HTFFR) at temperatures from 500 to 1300 K.Laser-induced fluorescence was used to monitor relative . k(T) was determined to be (2.5 +/- 1.3) * 10-14 exp cm3 molecule-1 s-1 (confidence level > 95percent).The reaction probably proceeds via an intermediate complex which preferentially dissociates to the reactants.The negative activation energy implies D(O-AlO) >/= D(O-CO) = 127 kcal mol-1, which is incompatible with the O-AlO dissociation energy obtained for AlO2 from Al2O3 evaporation-mass spectrometry studies.It is argued that the latter AlO2 may have a different structure from that of the present work.
Reactions of Pulsed-Laser Evaporated Aluminium Atoms with Oxygen. Infrared Spectra of the Reaction Products in Solid Argon
Andrews, Lester,Burkholder, Thomas R.,Yustein, Jason T.
, p. 10182 - 10189 (2007/10/02)
Reactions of pulsed-laser evaporated Al atoms with O2 in a condensing argon stream gave cyclic-AlO2 at 496.3 cm-1 as the major product.In addition sharp new absorptions at 1211.2, 1176.3, and 1129.5 cm-1 are identified on the basis of isotopic shifts and multiplets as linear OAlOAlO, AlOAlO, and OAlO, respectively.The identification of linear OAlOAlO and AlOAlO was confirmed by MP2 calculations of isotopic frequencies.The 1129.5 cm-1 band exhibited a sharp mixed oxygen isotopic triplet and isotopic ratio 1.0261 in agreement with that expected for a linear molecule.A sharp 1092.5 cm-1 absorption is identified as OAlOO on the basis of a mixed oxygen isotopic quartet with 16O2/16O18O/18O2 and 16O2/18O2 reagent mixtures.The only AlO2 isomers observed were the cyclic and linear forms found by theory to be potential minima.The observation of isotopic shifts and mixed isotopic multiplets is absolutely essential for the identification of new transient species.
Raman spectra of the products of the Al + O2 reaction in inert matrices. Possible structure of the Al2O3 molecule
Rozhanskii, I. L.,Serebrennikov, L. V.,Shevel'kov, A. F.
, p. 276 - 277 (2007/10/02)
We have obtained the Raman spectra of the molecules produced by the interaction of Al with O2 in argon and in nitrogen matrices.In the spectra for the Ar matrices we observed bands assigned to totally symmetric vibrations of the Al2O and Al(O2)(cycl.) molecules, and of various polymers of composition (AlO)n.In the spectra for the nitrogen matrices a doublet at 1031, 1024 cm-1 assigned to ν1 of the Al2O3 molecule, is additionally observed.By comparing these results with the i.r. spectra of the system we have calculated the force field of the Al2O3 molecule and we have proposed a model of its structure.
