111009-19-9Relevant academic research and scientific papers
REGIOSPECIFIC PREPARATION AND ALLYLATION OF FLUOROMETHYL KETONE ENOL ETHERS VIA FLUORO-OLEFINATION OF 1,2,3-TRIOL DERIVATIVES
Shimizu, Makoto,Nakahara, Yuko,Kanemoto,Shigekazu,Yoshioka, Hirosuke
, p. 1677 - 1680 (1987)
Fluoromethyl ketone enol ethers are regiospecifically prepared in good yields by treatment of 2-alkoxy-1,3-bis(t-butyldimethylsiloxy)alkene with TBAF-MsF, and subsequent thermal (3,3)-sigmatropic rearrangement on the 2-alkenyl enol ethers gives α-allylate
