REGIOSPECIFIC PREPARATION AND ALLYLATION OF FLUOROMETHYL KETONE ENOL ETHERS VIA FLUORO-OLEFINATION OF 1,2,3-TRIOL DERIVATIVES

DOI: 10.1016/S0040-4039(00)95392-9

Source and publish data:

Tetrahedron Letters p. 1677 - 1680 (1987)

Update date:2022-07-30

Topics: Allylation

Authors:

Shimizu, Makoto

Nakahara, Yuko

Kanemoto,Shigekazu

Yoshioka, Hirosuke

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Article abstract of DOI:10.1016/S0040-4039(00)95392-9

Fluoromethyl ketone enol ethers are regiospecifically prepared in good yields by treatment of 2-alkoxy-1,3-bis(t-butyldimethylsiloxy)alkene with TBAF-MsF, and subsequent thermal (3,3)-sigmatropic rearrangement on the 2-alkenyl enol ethers gives α-allylate

Full text of DOI:10.1016/S0040-4039(00)95392-9

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