111114-34-2

Basic information

• Product Name: Phosphonium, (1-methyl-2-oxobutyl)triphenyl-, bromide
• CAS NO: 111114-34-2
• Molecular Formula: C23H24OP.Br
• Molecular Weight: 427.321
• Mol File: 111114-34-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphonium, (1-methyl-2-oxobutyl)triphenyl-, bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonium, (1-methyl-2-oxobutyl)triphenyl-, bromide(111114-34-2)
• EPA Substance Registry System: Phosphonium, (1-methyl-2-oxobutyl)triphenyl-, bromide(111114-34-2)

Safety Data

• Hazardous Substances Data: 111114-34-2(Hazardous Substances Data)

Upstream product

• 815-52-1 2-bromopentan-3-one 
• 603-35-0 triphenylphosphine 
• 96-22-0 pentan-3-one 

Downstream Products

• 83188-34-5 4-methyl-6-phenylhexa-4,5-dien-3-one 
• 72522-40-8 (4RS,6SR,7SR)-Serricornin 
• 72598-35-7 (-)-serricornin 
• 72522-40-8 (4R,6S,7S)-7-hydroxy-4,6-dimethyl-3-nonanone 
• 350246-40-1 (7S,8R,8aS,6E)-7,8-Dihydroxy-8-methyl-[(2R,4E,6S)-2,5-dimethyl-6-benzyloxymethyloxy-4-octenylidene]octahydroindolizidine 
• 350246-39-8 (8R,8aS,6E)-8-Hydroxy-8-methyl-[(2R,4E,6S)-2,5-dimethyl-6-benzyloxymethyloxy-4-octenylidene]octahydroindolizin-7-done 
• 350246-38-7 (8R,8aS)-6-((E)-(2R,6S)-6-Benzyloxymethoxy-1-hydroxy-2,5-dimethyl-oct-4-enyl)-8-hydroxy-8-methyl-hexahydro-indolizin-7-one 
• 350246-36-5 (2R,6S,4E)-6-Benzyloxymethyloxy-1-(tert-butyldiphenylsiloxy)-2,5-dimethyl-4-octene 
• 350246-35-4 (2R,6S,4E)-1-(tert-Butyldiphenylsiloxy)-2,5-dimethyl-4-octen-6-ol 
• 350246-34-3 (2R,4E)-1-(tert-Butyldiphenylsiloxy)-2,5-dimethyl-4-octen-6-one 
• 350246-37-6 (2R,6S,4E)-6-Benzyloxymethyloxy-2,5-dimethyl-4-octen-1-ol 
• 350246-24-1 (2R,6S,4E)-6-Benzyloxymethyloxy-2,5-dimethyl-4-octen-1-al 
• 111114-35-3 triphenyl-(1-propionylethylidene)phosphorane 

Relevant articles and documents

Rasta Resin-TBD-Catalyzed γ-Selective Morita-Baylis-Hillman Reactions of α,γ-Disubstituted Allenones

Rasta resin-TBD (RR-TBD) was found to be an efficient organocatalyst for γ-selective Morita-Baylis-Hillman reactions between α,γ-disubstituted allenones and aryl aldehydes. In these reactions the heterogeneous nature of RR-TBD greatly facilitated product isolation since the catalyst could be separated simply by filtration.

Facile synthesis of (-)-serricornin by means of palladium-catalyzed hydrogenolysis of alkenyloxiranes

Chiral synthesis of (-)-serricornin by using palladium-catalyzed stereoselective hydrogenolysis of the alkenyloxirane to the homoallylic alcohol with formic acid as a key step was carried out.