83188-34-5Relevant academic research and scientific papers
Rasta Resin-TBD-Catalyzed γ-Selective Morita-Baylis-Hillman Reactions of α,γ-Disubstituted Allenones
Ma, Shuang,Yang, Yun-Chin,Toy, Patrick H.
supporting information, p. 1732 - 1736 (2015/07/20)
Rasta resin-TBD (RR-TBD) was found to be an efficient organocatalyst for γ-selective Morita-Baylis-Hillman reactions between α,γ-disubstituted allenones and aryl aldehydes. In these reactions the heterogeneous nature of RR-TBD greatly facilitated product isolation since the catalyst could be separated simply by filtration.
CHLOROACETYLENES AS MICHAEL ACCEPTORS. II. DIRECT ETHYNYLATION AND VINYLATION OF TERTIARY ENOLATES.
Kende, Andrew S.,Fludzinski, Pawel
, p. 2373 - 2376 (2007/10/02)
The reaction of ClCCCl, PhCCCl and PhSCCCl with a variety of tertiary enolates leads in 43-90percent yields to α-chloroethynyl, α-phenylethynyl and α-thiophenylethynyl derivatives.The -CCCl group is smoothly converted to -CCH using copper p
