111193-60-3

Basic information

• Product Name: (2S,3R,4S)-N-benzyloxycarbonyl-3,4-dihydroxyproline methyl ester
• CAS NO: 111193-60-3
• Molecular Weight: 295.292
• Mol File: 111193-60-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S)-N-benzyloxycarbonyl-3,4-dihydroxyproline methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S)-N-benzyloxycarbonyl-3,4-dihydroxyproline methyl ester(111193-60-3)
• EPA Substance Registry System: (2S,3R,4S)-N-benzyloxycarbonyl-3,4-dihydroxyproline methyl ester(111193-60-3)

Safety Data

• Hazardous Substances Data: 111193-60-3(Hazardous Substances Data)

Upstream product

• 5211-24-5 (2S)-2,5-dihydro-1H-pyrrole-1,2-dicarboxylic acid 2-methyl 1-(phenylmethyl) ester 
• 57653-38-0 N-<(phenylmethoxy)carbonyl>-4(R)-<<(4-methylphenyl)sulfonyl>oxy>-(S)-proline methyl ester 
• 13504-85-3 (2S,4R)-1-(benzyloxycarbonyl)-4-hydroxypyrrolidine-2-carboxylic acid 
• 186145-08-4 (2S)-2,5-dihydro-1H-pyrrole-2-carboxylate hydrochloride 
• 84062-30-6 methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate 
• 64187-48-0 methyl (2S,4R)-1-benzyloxycarbonyl-4-hydroxypyrrolidine-2-carboxylate 
• 13139-17-8 N-(Benzyloxycarbonyloxy)succinimide 
• 1499-56-5 (R)-4-hydroxy-L-proline ethyl ester 

Downstream Products

• 111193-62-5 (2S,3R,4S)-N-benzyloxycarbonyl-3,4-dihydroxyproline-3,4-isopropylidene acetal methyl ester 
• 111193-64-7 methyl 1-benzyloxycarbonyl-(3S,4R)-isopropylidenedioxy-(2S)-pyrrolidinylcarboxylate 
• 105990-41-8 (2R,3R,4S)-2-hydroxymethylpyrrolidine-3,4-diol 
• 111265-96-4 (2R,3R,4S)-1-(benzyloxycarbonyl)-2-(hydroxymethyl)pyrrolidine-3,4-diol 3,4-O-isopropylidene acetal 
• 160711-63-7 (2R,3R,4S)-1-benzyloxycarbonyl-2-hydroxymethylpyrrolidine-3,4-diol 
• 111193-68-1 (3aR,4S,6aS)-2,2-Dimethyl-4-methylsulfanylmethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester 
• 111193-67-0 (3aR,4S,6aS)-4-((S)-3-Amino-3-carboxy-propylsulfanylmethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester 
• 111193-66-9 (3aR,4R,6aS)-2,2-Dimethyl-4-(toluene-4-sulfonyloxymethyl)-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester 

Relevant articles and documents

Synthesis of (2R,3R,4S)-2-hydroxymethylpyrrolidine-3,4-diol from (2S)-3,4-dehydroproline derivatives

(2R,3R,4S)-2-Hydroxymethylpyrrolidine-3,4-diol (1,4-dideoxy-1,4-imino-D-ribitol) was synthesized in five steps from N-protected (2S)-3,4-dehydroproline methyl esters.The stereoselective reaction of osmium tetraoxide with dehydroproline derivatives gave hi