111194-18-4

Basic information

• Product Name: (R)-Hydroxy-((2R,4S,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-acetic acid 2-trimethylsilanyl-ethyl ester
• CAS NO: 111194-18-4
• Molecular Weight: 487.57
• Mol File: 111194-18-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-Hydroxy-((2R,4S,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-acetic acid 2-trimethylsilanyl-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-Hydroxy-((2R,4S,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-acetic acid 2-trimethylsilanyl-ethyl ester(111194-18-4)
• EPA Substance Registry System: (R)-Hydroxy-((2R,4S,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-acetic acid 2-trimethylsilanyl-ethyl ester(111194-18-4)

Safety Data

• Hazardous Substances Data: 111194-18-4(Hazardous Substances Data)

Upstream product

• 79414-13-4 trimethylsilylethyl bromoacetate 
• 111194-16-2 ((4S,5R,6R)-2-Hydroxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-(1-methoxy-1-methyl-ethoxy)-acetic acid 2-trimethylsilanyl-ethyl ester 
• 111194-12-8 (4S*,5R*,6R*)-5,6-dimethyl-4-phenylselenomethyltetrahydro-2H-pyran-2-one 
• 111194-15-1 2-trimethylsilylethyl 2-(2-methyl-2-methoxyethoxy)ethanoate 
• 111194-13-9 2-trimethylsilylethyl 2-formyloxyethanoate 
• 111194-14-0 2-hydroxy-O-(2-trimethylsilylethyl)ethanoate 
• 71816-81-4 (+/-)-cis-5,6-dimethyl-5,6-dihydro-2H-pyran-2-one 
• 66186-46-7 (4R*,5R*)-4-methyl-5-hydroxy-2-hexynoic acid 
• 41998-65-6 (2R*,3R*)-3-methyl-4-pentyne-2-ol 
• 20343-90-2 bis(phenylseleno)methane 
• 2916-68-9 2-(Trimethylsilyl)ethanol 
• 67-56-1 methanol 
• 111194-17-3 Hydroxy-((4S,5R,6R)-2-hydroxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-acetic acid 2-trimethylsilanyl-ethyl ester 

Downstream Products

• 104432-03-3 (+/-)-benzoylselenopederic acid 
• 111194-20-8 ((2R,4S,5R,6R)-2-Methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-oxo-acetic acid 2-trimethylsilanyl-ethyl ester 
• 129156-14-5 Benzoic acid (S)-((2R,4S,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-(2-trimethylsilanyl-ethoxycarbonyl)-methyl ester 

Relevant articles and documents

STUDIES RELATED TO THE SYNTHESIS OF (+/-)-PEDERIN. PART 1. SYNTHESIS OF ETHYL PEDERATE AND BENZOYLSELENOPEDERIC ACID.

The first in a series of 2 papers on the synthesis of the insect toxin pederin (1) begins with a discussion of synthesis of the ring A fragments (+/-) pederate (2) and (+/-)-benzoylselenopederic acid (4).A silicon-mediated intramolecular cyclisation of a