1112-91-0

Basic information

• Product Name: METHYLTRIALLYLSILANE
• Synonyms: METHYLTRIALLYLSILANE;Methyltriallysilane;triallylmethylsilane;Methyltriallylsilane,97%
• CAS NO: 1112-91-0
• Molecular Formula: C10H18Si
• Molecular Weight: 166.34
• Mol File: 1112-91-0.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 95 °C (52 mmHg)
• Flash Point: 22 °C
• Appearance: /
• Density: 0.775g/cm³
• Vapor Pressure: 1.88mmHg at 25°C
• Refractive Index: 1.4661-1.4681
• Storage Temp.: Flammables area
• CAS DataBase Reference: METHYLTRIALLYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYLTRIALLYLSILANE(1112-91-0)
• EPA Substance Registry System: METHYLTRIALLYLSILANE(1112-91-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38-10
• Safety Statements: 37/39-26-16
• RIDADR: UN 1993 3/PG III
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 1112-91-0(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

InChI:InChI=1/C10H18Si/c1-5-8-11(4,9-6-2)10-7-3/h5-7H,1-3,8-10H2,4H3

Upstream product

• 75-79-6 Methyltrichlorosilane 
• 1730-25-2 allylmagnesium bromide 
• 102129-44-2 sodium bis(1,2-benzenediolato)methylsilicate 
• 556-56-9 allyl iodid 
• 1873-92-3 allyldichloromethylsilane 
• 106-95-6 allyl bromide 
• 346713-20-0 allylsamarium bromide 
• 2622-05-1 allylmagnesium bromide 

Relevant articles and documents

Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work. This journal is the Partner Organisations 2014.

Reactivity of Hypervalent Species: Reactions of Anionic Penta-Coordinated Silicon Complexes towards Nucleophiles

The reactivity of anionic penta-coordinated silicon complexes 4-O)2>-Na+ 1 with nucleophilic reagents has been studied. 1 can be reduced to organosilanes RSiH3 by metallic hydrides.Reactions with an excess of Grignard or organolithium reagents (R'MgX or R'Li) gave tetraorganosilanes RSiR'3.When only two molar equivalents of Grignard reagents (R'MgX) or lithium reagents (R'Li) are added to complexs 1 functional silanes RR'2SiX can be prepared.

Reaktivitaet von anionischen, fuenffach koordinierten Si-Komplexen gegenueber Nucleophilen

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