1112130-83-2

Upstream product

• 194800-71-0 (Z)-2-fluoro-3-(4-methoxyphenyl)acrylaldehyde 
• 343338-28-3 (S)-2-methylpropane-2-sulfinamide 
• 123-11-5 4-methoxy-benzaldehyde 
• 830-02-4 (2Z)-2-fluoro-3-(4-methoxyphenyl)-2-propen-1-ol 
• 26927-88-8 (Z)-3-(4-methoxyphenyl)-2-fluoroacrylic acid ethyl ester 

Downstream Products

• 1112131-14-2 N-[(Z)-2-fluoro-1-isopropyl-3-(4-methoxyphenyl)-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112131-10-8 N-[(Z)-2-fluoro-1-isopropyl-3-(4-methoxyphenyl)-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112131-17-5 N-[(Z)-2-fluoro-1-isobutyl-3-(4-methoxyphenyl)-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112131-26-6 N-[(Z)-2-fluoro-3-(4-methoxyphenyl)-1-vinyl-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112131-02-8 N-[(Z)-2-fluoro-3-(4-methoxyphenyl)-1-phenyl-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112130-99-0 N-[(Z)-2-fluoro-3-(4-methoxyphenyl)-1-phenyl-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112131-20-0 N-[(Z)-1-benzyl-2-fluoro-3-(4-methoxyphenyl)-2-propenyl]-2-methyl-2-propanesulfinamide 
• 1112131-23-3 N-(1-[(Z)-1-fluoro-2-(4-methoxyphenyl)ethenyl]-3-butenyl)-2-methyl-2-propanesulfinamide 

Relevant academic research and scientific papers

Diastereocontrolled addition of organometallic reagents to S-chiral N-(tert-butanesulfinyl)-α-fluoroenimines

Grignard and organolithium reagents efficiently react with (S)-N-(tert-butanesulfinyl)-α-fluoroenimines to provide chiral allylamines in excellent yields and with diastereomeric ratios of up to 96:4. Acidic removal of the sulfinyl group and simple functio

Synthesis of fluorinated pseudopeptides: Metal mediated reversal of stereochemistry in diastereoselective addition of organometallic reagents to N-(tert-butanesulfinyl)-α-fluoroenimines

The addition reaction of organometallic reagents to N-(tert-butanesulfinyl) -α-fluoroenimines was studied. Depending of the nature of the organometallic species (Grignard reagents or zincate complexes), we were able to control the configuration of the new