1112908-15-2Relevant academic research and scientific papers
Copper-Catalyzed Aerobic Oxidative Regioselective Thiocyanation of Aromatics and Heteroaromatics
Jiang, Huanfeng,Yu, Wentao,Tang, Xiaodong,Li, Jianxiao,Wu, Wanqing
, p. 9312 - 9320 (2017/09/22)
A copper-catalyzed aerobic oxidative reaction between aromatics or heteroaromatics with KSCN is developed by using O2 as the oxidant. The combination of Cu(OTf)2, N,N,N′,N′-tetramethylethylenediamine (TMEDA) and BF3·Et2O provides an efficient catalytic system, affording substituted thiocyanation products and 2-aminobenzothiazoles in excellent yields. The reaction also possesses a good functional group tolerance for both strong electron-withdrawing and electron-donating groups.
Mn(OAc)3-promoted regioselective free radical thiocyanation of indoles and anilines
Pan, Xiang-Qiang,Lei, Mao-Yi,Zou, Jian-Ping,Zhang, Wei
experimental part, p. 347 - 349 (2009/04/19)
Mn(OAc)3-promoted free radical thiocyanations of indoles and arylamines are introduced. Reactions performed under mild conditions give regioselective products in good to excellent yields.
