111373-64-9

Upstream product

• 111373-58-1 2-[(1S,2R,4S,5R)-3-Benzyl-4-(2-hydroxy-2-phenyl-ethyl)-3-aza-bicyclo[3.2.0]hept-2-yl]-1-phenyl-ethanol 
• 111373-56-9 1-Phenyl-2-((2aS,2bR,4R,6S,6aR)-4-phenyl-octahydro-5-oxa-5a-aza-cyclobuta[a]pentalen-6-yl)-ethanol 
• 111373-61-6 (1S,2R,4S,5R)-2,4-Diphenethyl-3-aza-bicyclo[3.2.0]heptane 
• 100-42-5 styrene 
• 129413-75-8 (E)-(5-bromopent-3-en-1-yl)benzene 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

Utilization of Me3SiSnBu3-F- in Organic Synthesis. Reaction of an Allyl Anion Generated from Me3SiSnBu3 and CsF

The intramolecular cyclization of an allyl halide having a carbonyl group proceeded smoothly via an allyl anion in the presence of Me3SiSnBu3 and CsF in DMF.The resultant products were converted into useful compounds for the synthesis of natural products.

A Highly Stereoselective Synthesis of (E,E)-1,5-Dienes

Several representative 1,5-dienes were synthesized, with a high degree of regioselectivity, by a series of nitrone cycloadditions and subsequent deamination of the adducts.