111399-50-9

Basic information

• Product Name: Methylphenoxychloraluminium
• CAS NO: 111399-50-9
• Molecular Weight: 170.574
• Mol File: 111399-50-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methylphenoxychloraluminium(CAS DataBase Reference)
• NIST Chemistry Reference: Methylphenoxychloraluminium(111399-50-9)
• EPA Substance Registry System: Methylphenoxychloraluminium(111399-50-9)

Safety Data

• Hazardous Substances Data: 111399-50-9(Hazardous Substances Data)

Upstream product

• 917-65-7 methylaluminum dichloride 
• 100-66-3 methoxybenzene 

Relevant articles and documents

PHENOXYALUMINIUM COMPOUNDS. VI. COMPLEX AND REACTION MECHANISM OF METHYLALUMINIUM COMPOUNDS WITH ANISOLE

The reactions of anisole with organoaluminium compounds MenAlXn-1 have been investigated.The formation of a complex is the first reaction step, followed by cleavage and elimination of the gases MeX and small amounts of hydrocarbons.The yield of the gases and the cleavage rate decreases in the order: AlCl3>/=MeAlCl2>Me2AlCl>>Me3Al and Me2AlI>Me2AlCl>Me2AlBr.For most of the investigated reaction a marked decrease in gas evolution was observed after a short period of time.This is explained by the formation of an almost inactive mixed dimer (I) which at the (I) reaction temperature is more stable than the Me2(Cl)Al:O(Me)Ph complex.It is suggested that dimer I is formed after the intramolecular reaction of the 2:1 complex II after elimination of MeX. (II).