151477-85-9Relevant academic research and scientific papers
Heterocyclisation of free or partially protected alditols via their bis- cyclic sulfate derivatives. Versatile synthesis of aza and thiodeoxyanhydroalditol with erythro, threo, arabino, gulo, talo or manno configuration
Gla?on, Virginie,Benazza, Mohammed,Beaupère, Daniel,Demailly, Gilles
, p. 5053 - 5056 (2000)
The his-cyclic sulfate derivatives of erythritol (1), D,L-threito1 (5), 3,4-di-O-benzyl-D-mannitol (9), 1,2-O-isopropylidene-D-mannitol (14) and l-O- benzyl-D,L-xylito1 (18) were submitted to nucleophilic attack by allylamine or sodium sulfide. In both ca
Applications of Cyclic Sulfates of vic-Diols: Synthesis of Episulfides, Olefins, and Thio Sugars
Calvo-Flores, Francisco G.,Garcia-Mendoza, Pilar,Hernandez-Mateo, Fernando,Isac-Garcia, Joaquin,Santoyo-Gonzalez, Francisco
, p. 3944 - 3961 (2007/10/03)
A new efficient and expeditious one-pot synthesis of thiiranes and olefins from cyclic sulfates of inc-diols is described. Opening of cyclic sulfates with potassium thioacetate or potassium thiocyanate followed by treatment with sodium methoxide led to ep
STEREOSELECTIVE SYNTHESIS OF DIAMINO DIOL DERIVATIVES WITH C2-AXIS OF SYMMETRY
Yokomatsu, Tsutomu,Suemune, Kenji,Shibuya, Shiroshi
, p. 577 - 580 (2007/10/02)
An efficient and streocontrolled synthesis of C2-symmetric diamino diol derivatives (7) was achieved through selective opening of N-Boc bis-aziridine (6), prepared from D-mannitol via cyclic sulfate (4).
