111651-31-1

Basic information

• Product Name: [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate
• Synonyms: [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate
• CAS NO: 111651-31-1
• Molecular Weight: 470.519
• Mol File: 111651-31-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate(111651-31-1)
• EPA Substance Registry System: [(4R,4aR,8R,8aR)-4-(benzoyloxymethyl)-2,2,6,6-tetramethyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-8-yl]methyl benzoate(111651-31-1)

Safety Data

• Hazardous Substances Data: 111651-31-1(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 69-65-8 mannitol 
• 13443-46-4 L-iditol hexaacetate 
• 488-45-9 L-iditol 
• 5346-88-3 1,6-dibenzoyl-L-iditol 
• 77-76-9 2,2-dimethoxy-propane 
• 7226-27-9 1,6-di-O-benzoyl-D-mannitol 

Downstream Products

• 111651-33-3 4R,8R,9R,10R-2,2',6,6'-tetramethyl-4,8-bis(p-tolylsulphonyloxymethyl)-1,3,5,7-tetraoxadecalin 
• 863718-22-3 (4S,4aS,8S,8aS)-4,8-Bis-chloromethyl-2,2,6,6-tetramethyl-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxine 

Relevant articles and documents

SYNTHESIS AND CONFORMATIONS OF 2,3:4,5- AND 2,4:3,5-DI-O-ISOPROPYLIDENE-D-MANNITOL

The 2,3:4,5- (8) and 2,4:3,5-di-O-isopropylidene (10) derivatives of D-mannitol have been prepared from 1,6-di-O-benzoyl-D-mannitol and their structures established by (13)C-n.m.r. spectroscopy.The 1,3-dioxane rings in 10 adopt a skew conformation and the sugar carbon chain in 8 is bent around the C-3-C-4 bond, as found by i.r. data and molecular mechanics calculations.Oxidation of 8 with pyridinium dichromate gave 2,3:4,5-di-O-isopropylidene-D-mannono-1,6-lactone (12).

An iterative acetylene-epoxide coupling strategy for the total synthesis of longimicin C

Longimicin C, a naturally occurring annonaceous acetogenin possessing a C2-symmetrical bis-THF moiety and a short hydrocarbon chain between its THF-containing region and a terminal γ-lactone, was synthesized for the first time. The total synthe