111689-73-7Relevant academic research and scientific papers
Deblocking of dithioacetals and oxathioacetals using periodic acid under mild nonaqueous conditions
Shi, Xiao-Xin,Khanapure, Subhash P.,Rokach, Joshua
, p. 4331 - 4334 (1996)
A novel method for the deblocking of the dithioacetals and oxathioacetals is described. Periodic acid under nonaqueous conditions has been used for the deprotection of the dithio- and oxathio-derivatives to the corresponding carbonyl compounds. This simple high-yield transformation is conveniently carried out in nonaqueous medium and works well with complex sensitive aldehydes and in the presence of other protective groups.
