1118-39-4

Basic information

• Product Name: PSEUDO LINALYL ACETATE
• Synonyms: 2-methyl-6-methylene-7-octen-2-oacetate;2-methyl-6-methylene-7-octen-2-ylacetate;3-methylene-7-methyl-1-octen-7-ylacetate;aceticacid,2-methyl-6-methylene-7-octen-2-ylester;aceticacid,myrcenylester;myrcenyl;2-ACETOXY-2-METHYL-6-METHYLENE-7-OCTENE;7-OCTEN-2-OL, 2-METHYL-6-METHYLENE:ACETATE
• CAS NO: 1118-39-4
• Molecular Formula: C₁₂H₂₀O₂
• Molecular Weight: 196.29
• EINECS: 214-262-0
• Mol File: 1118-39-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 273.19°C (rough estimate)
• Flash Point: 90.4°C
• Appearance: /
• Density: 0.9884 (rough estimate)
• Vapor Pressure: 0.0147mmHg at 25°C
• Refractive Index: 1.4480 (estimate)
• Water Solubility: 49.6mg/L at 24℃
• CAS DataBase Reference: PSEUDO LINALYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: PSEUDO LINALYL ACETATE(1118-39-4)
• EPA Substance Registry System: PSEUDO LINALYL ACETATE(1118-39-4)

Safety Data

• Hazardous Substances Data: 1118-39-4(Hazardous Substances Data)

Usage

Occurrence

Has apparently not been reported to occur in nature

Preparation

By cold acetylation of myrcenol (Arctander, 1969).

Flammability and Explosibility

Nonflammable

Safety Profile

Mildly toxic by ingestion. A skinirritant. When heated to decomposition itemits acrid smoke and irritating fumes.

InChI:InChI=1/C12H20O2/c1-6-10(2)8-7-9-12(4,5)14-11(3)13/h6H,1-2,7-9H2,3-5H3

Upstream product

• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 64-19-7 acetic acid 
• 543-39-5 myrcenol 
• 75-36-5 acetyl chloride 
• 76280-57-4 Acetic acid 2-bromo-1,1-dimethyl-5-methylene-hept-6-enyl ester 

Downstream Products

• 543-39-5 myrcenol 
• 53144-54-0 1-(8,8-dimethyl-1,2,3,4,6,7,8,8a-octahydro-[2]naphthyl)-ethanone 

Relevant articles and documents

Ruthenium-Catalyzed Cross Metathesis of β-Myrcene and its Derivatives with Methyl Acrylate

The reaction of β-myrcene with methyl acrylate produces 3-methylenecyclopent-1-ene in the presence of the Ru catalyst Neolyst M2 by ring-closing metathesis in the first step. In the second step, the generated methylidene unit reacts with methyl acrylate to give the corresponding unsaturated cyclic ester by cross metathesis. Under the optimized reaction conditions (80 °C, Neolyst M2, 16 equivalents of methyl acrylate), derivatives of β-myrcene, myrcenol, myrcenyl acetate, and β-ocimene, react to yield functionalized acyclic esters.

Zur Reaktion von Myrcen mit N-Bromsuccinimid in Gegenwart von Wasser, Eisessig oder Alkoholen

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