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111865-42-0

1,3-Dioxane, 2,2'-(1,4-butanediyl)bis- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 111865-42-0 Structure

  • Basic information

    1. Product Name: 1,3-Dioxane, 2,2'-(1,4-butanediyl)bis-
    2. Synonyms:
    3. CAS NO:111865-42-0
    4. Molecular Formula: C12H22O4
    5. Molecular Weight: 230.304
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 111865-42-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,3-Dioxane, 2,2'-(1,4-butanediyl)bis-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,3-Dioxane, 2,2'-(1,4-butanediyl)bis-(111865-42-0)
    11. EPA Substance Registry System: 1,3-Dioxane, 2,2'-(1,4-butanediyl)bis-(111865-42-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 111865-42-0(Hazardous Substances Data)

111865-42-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 111865-42-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,1,8,6 and 5 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 111865-42:
(8*1)+(7*1)+(6*1)+(5*8)+(4*6)+(3*5)+(2*4)+(1*2)=110
110 % 10 = 0
So 111865-42-0 is a valid CAS Registry Number.

111865-42-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-[4-(1,3-dioxan-2-yl)butyl]-1,3-dioxane

1.2 Other means of identification

Product number -
Other names 1,4-di(1,3-dioxan-2-yl)butane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:111865-42-0 SDS

111865-42-0Downstream Products

111865-42-0Relevant articles and documents

Oxidative coupling reactions of grignard reagents with nitrous oxide

Kiefer, Gregor,Jeanbourquin, Loic,Severin, Kay

, p. 6302 - 6305 (2013)

Catalysis with laughing gas: N2O in combination with transition-metal catalysts allow the oxidative homo- and cross-coupling of Grignard reagents. The reactions can be performed under mild conditions despite the inert character of N2O. Copyright

Fe-catalysed Kumada-type alkyl-alkyl cross-coupling. Evidence for the intermediacy of Fe(i) complexes

Guisan-Ceinos, Manuel,Tato, Francisco,Bunuel, Elena,Calle, Paloma,Cardenas, Diego J.

, p. 1098 - 1104 (2013/06/04)

A novel Fe-NHC catalytic system allows the alkyl-alkyl cross-coupling reaction of alkyl halides and alkylmagnesium reagents has been developed. To our knowledge, this is the first Fe-catalysed Kumada-type coupling for the formation of C(sp3)-C(sp3) bonds in the presence of functional groups. The process takes place under mild conditions, avoiding the formation of β-elimination products. Mechanistic studies suggest the intermediacy of Fe(i) complexes, formed by reduction with the Grignard reagent, as the active species.

Concise total syntheses of the sesquiterpenoids (-)-homalomenol A and (-)-homalomenol B

Piers, Edward,Oballa, Renata M.

, p. 8439 - 8447 (2007/10/03)

The conjugate additions of the organocopper(I) reagents 22 and 27 to the enantiomerically homogeneous bicyclic enone 4 provided, after epimerization (NaOMe, MeOH) of the resultant product mixtures and appropriate chromatographic separations, the bicyclo[4.3.0]nonan-2-ones 24 and 28. Compounds 24 and 28 were readily converted, via two synthetic steps in each case, into the sesquiterpenoids (-)-homalomenols B (2) and A (1), respectively.

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